Poly(N-methylpyrrole) electrodeposited on copper: Corrosion protection properties

被引：31

作者：

Redondo, M. L. ^{[1
]}

Sanchez de la Blanca, E. ^{[1
]}

Garcia, M. V. ^{[1
]}

Gonzalez-Tejera, M. J. ^{[1
]}

机构：

[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Quim Fis 1, E-28040 Madrid, Spain

来源：

PROGRESS IN ORGANIC COATINGS | 2009年 / 65卷 / 03期

关键词：

Corrosion protection; Conducting polymers; Poly(N-methylpyrrole); ELECTROCHEMICAL SYNTHESIS; POLYPYRROLE FILMS; AQUEOUS-SOLUTION; PYRROLE; ELECTROPOLYMERIZATION; BRASS; PERFORMANCE; IMPEDANCE; COATINGS; BEHAVIOR;

D O I：

10.1016/j.porgcoat.2009.03.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Electrochemical synthesis of poly(N-methylpyrrole) films on copper electrodes from an aqueous oxalic acid has been achieved. A potential higher than 2 V (SCE) was needed to generate the polymer, for this reason, the polymer was in the overoxidized state. The inhibiting corrosion properties of this coating on copper were investigated for the first time in aqueous 0.1 M sodium chloride solution using potentiodynamic polarization, Tafel analyses. open-circuit potential and electrochemical impedance spectroscopy. Corrosion protection properties comparable to those of polypyrrole (PPy) films were observed for these films. A physical barrier effect is the most likely protection mechanism. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：386 / 391

页数：6

共 50 条

[41] Torsions of N-methylpyrrole and its cation
Davies, Alexander R.
Kemp, David J.
Wright, Timothy G.
CHEMICAL PHYSICS LETTERS, 2021, 763
[42] Microgel particles as a matrix for polymerization:: A study of poly(N-isopropylacrylamide)-poly(N-methylpyrrole) dispersions
Mrkic, J
Saunders, BR
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 222 (01) : 75 - 82
[43] Preparation and Characterization of Poly(N-Methylpyrrole)/MoO3 Hybrid Composites
Sanchez-Jimenez, Margarita
Estrany, Francesc
Aleman, Carlos
POLYMER-PLASTICS TECHNOLOGY AND ENGINEERING, 2017, 56 (15) : 1704 - 1712
[44] Nitrate Ion Selective Electrode Based on Ion Imprinted Poly(N-methylpyrrole)
Bomar, Ellen M.
Owens, George S.
Murray, George M.
CHEMOSENSORS, 2017, 5 (01)
[45] DIRECT FLUORINATION OF THIOPHENE AND N-METHYLPYRROLE
CRESTONI, ME
FORNARINI, S
GAZZETTA CHIMICA ITALIANA, 1989, 119 (03): : 203 - 204
[46] EMISSION SPECTRUM OF UNDECOMPOSED N-METHYLPYRROLE
MILAZZO, G
JOURNAL OF CHEMICAL PHYSICS, 1953, 21 (01): : 163 - 164
[47] Charge transport processes in electrochemically deposited poly(pyrrole) and poly(N-methylpyrrole) thin films
Kim, JJ
Amemiya, T
Tryk, DA
Hashimoto, K
Fujishima, A
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 416 (1-2): : 113 - 119
[48] The preparation of poly(N-methylpyrrole) bilayers with entrapped anthraquinone-2-sulfonate
Pyo, M
Kim, H
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1997, 18 (11) : 1195 - 1199
[49] Effect of strong magnetic fields on the photocurrent of a poly(N-methylpyrrole) modified electrode
Konno, A
Mogi, I
Watanabe, K
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2001, 507 (1-2): : 202 - 205
[50] Synthesis and characterization of poly(N-methylpyrrole)/TiO2 composites on steel
Mahmoudian, M. R.
Basirun, W. J.
Alias, Y.
APPLIED SURFACE SCIENCE, 2011, 257 (08) : 3702 - 3708

← 1 2 3 4 5 →