Evaluation of structural, spectral, thermal and optical properties of an efficient centrosymmetric organic single crystal 2-[2-(4-diethylamino-phenyl)-vinyl]-1-methyl pyridinium tetrafluoroborate for nonlinear optical applications

被引：16
|
作者：
Nivetha, K. [1 ]
Aravinth, K. [2 ]
Senthil, K. [3 ]
Kalainathan, S. [4 ]
机构：
[1] Vivekanandha Coll Arts & Sci Women Autonomous, Dept Chem, Tiruchengode 637205, Namakkal, India
[2] Sri Sivasubramaniya Nadar Coll Engn, Dept Phys, Chennai 603110, Tamil Nadu, India
[3] Xi An Jiao Tong Univ, State Key Lab Mech Behav Mat, Xian 710049, Peoples R China
[4] Vellore Inst Technol, Ctr Crystal Growth, Vellore 632014, Tamil Nadu, India
来源：
JOURNAL OF MOLECULAR STRUCTURE | 2021年 / 1225卷
关键词：
Stilbazolium derivative; Tetrafluoroborate; Crystal growth; Centrosymmetric structure; Laser damage threshold; Z-scan technique; GROWTH;
D O I：
10.1016/j.molstruc.2020.129082
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the present work, a novel ?conjugated stilbazolium chromophore of 2-[2-(4-diethylamino-phenyl)vinyl]-1-methyl pyridinium tetrafluoroborate (DESTB) has been synthesized and grown by slow solvent evaporation technique. Single crystal X-ray diffraction demonstrates that DESTB crystallizes in centrosymmetric monoclinic system with the space group P21/C. The different vibrational modes of DESTB were confirmed by Fourier transform infrared analysis. The thermal properties of DESTB sample were analyzed using TG/DTA techniques. The optical properties of DESTB crystal such as absorbance, photoluminescence, and laser damage threshold have been studied. Further the material is characterized by Z-scan technique with a He-Ne continuous wave laser at 632.8 nm to measure the third order nonlinear optical properties of DESTB crystal. (C) 2020 Elsevier B.V. All rights reserved.
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页数：7
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