Ceria-Containing Ordered Mesoporous Silica: Synthesis, Properties, and Applications

被引:33
|
作者
Pal, Nabanita [1 ]
Cho, Eun-Bum [2 ]
Patra, Astam K. [3 ]
Kim, Dukjoon [3 ]
机构
[1] Saha Inst Nucl Phys, Surface Phys & Mat Sci Div, Block 1-AF, Kolkata 700064, India
[2] Seoul Natl Univ Sci & Technol, Dept Fine Chem, Seoul 01811, South Korea
[3] Sungkyunkwan Univ, Sch Chem Engn, Suwon 16419, Kyunggi, South Korea
基金
新加坡国家研究基金会;
关键词
acid-catalyzed reactions; ceria; mesoporous materials; silica; template-directed synthesis; ORGANIC-INORGANIC HYBRID; SURFACTANT-ASSISTED SYNTHESIS; PHOTOCATALYTIC ACTIVITY; HYDROGEN-PRODUCTION; MOLECULAR-SIEVES; VISIBLE-LIGHT; SOLVENT-FREE; CATALYTIC PERFORMANCE; EFFICIENT CATALYST; CEO2; NANOPARTICLES;
D O I
10.1002/cctc.201500780
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Structural architecture and unique physical, chemical, thermal, and mechanical properties of ordered mesoporous silica materials can be tuned. High flexibility of silica materials can provide good support for different metal nanoparticles, metal oxides, and organic functional groups. The properties of silica materials can vary to a great extent by introducing the optimum amount of metal species co-doped, dispersed or composites with the silica mesostructure. The present study investigates the deposition of Ce-III/IV/CeO2 on the silica surface by using different wet chemical engineering methods, illustrates the syntheses of those ceria-silica or metal doped ceria-silica nanomaterials and offers clear picture of the influence that incorporated ceria concentration has on the properties of the support material. Ceria-silica based ordered mesoporous materials can have numerous applications is also discussed in this article, emphasizing its use as a heterogeneous catalyst in particular.
引用
收藏
页码:285 / 303
页数:19
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