Study on Fluorine-Containing Polyurethane Elastomers Based on 2,2-Bis[4-(4-amino-2-trifluoromethylphenoxy) phenyl]hexafluoropropane

被引:0
|
作者
Xu, Wenzong [1 ,2 ]
Liu, Liang [1 ]
Wang, Shaoqing [1 ]
Hu, Yuan [2 ]
机构
[1] Anhui Jianzhu Univ, Sch Mat Sci & Chem Engn, Hefei 230022, Anhui, Peoples R China
[2] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金;
关键词
Fluorinated diamine; Fluorinated polyurethane elastomer; Surface properties; Flame retardancy;
D O I
10.14233/ajchem.2014.17222
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A series of fluorine-containing polyurethane elastomers (FPUEs) were synthesized from 2,2-bis[4-(4-amino-2-trifluoromethylphenoxy)phenyl] hexafluoropropane (BAFPF(6)P), which was made from 2-chlorobenzotrifluoride and 2,2-bis(4-hydroxyphenyl) hexafluoropropane and characterized by Fourier transform infrared spectroscopy, nuclear magnetic resonance, thermogravimetric analysis, microscale combustion colorimeter and contact angle measurement. The results show that the fluorine-containing polyurethane elastomers prepared from BAFPF(6)P have good thermal stability and low surface tension. Furthermore, fluorine-containing polyurethane elastomers also exhibit good flame retardance and the peak heat release rate and total heat released of fluorine-containing polyurethane elastomer based on BAFPF(6)P are much lower than those of polyurethane elastomer without the fluorine element.
引用
收藏
页码:1324 / 1326
页数:3
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