Complex single-chain polymer topologies locked by positionable twin disulfide cyclic bridges

被引：42

作者：

Shishkan, Olga ^{[1
]}

Zamfir, Mirela ^{[1
]}

Gauthier, Marc Andre ^{[2
]}

Boerner, Hans G. ^{[3
]}

Lutz, Jean-Francois ^{[1
]}

机构：

[1] Inst Charles Sadron, Precis Macromol Chem Grp, F-67034 Strasbourg 2, France

[2] Inst Natl Rech Sci Energie Mat, Telecommun Res Ctr, Varennes, PQ J3X 1S2, Canada

[3] Humboldt Univ, Dept Chem, Lab Organ Synth Funct Syst, D-12489 Berlin, Germany

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 13期

基金：

欧洲研究理事会;

关键词：

SYNTHETIC-POLYMERS; NANOPARTICLES; SEQUENCE; CHEMISTRY; STRATEGIES; COVALENT; MONOMERS; CLICK;

D O I：

10.1039/c3cc47807f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oligomers containing the peptide sequence cysteine-any-cysteine (CXC) were attached, at specific locations, to a linear chain of polystyrene. The polymer-bound peptide motifs were then oxidized under dilute conditions to afford a complex bio-hybrid bi-cyclic topology via intramolecular twin disulfide bridge formation.

引用

页码：1570 / 1572

页数：3

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