Lateral adsorption geometry and site-specific electronic structure of a large organic chemisorbate on a metal surface

被引：121

作者：

Kraft, A.

Temirov, R.

Henze, S. K. M.

Soubatch, S.

Rohlfing, M.

Tautz, F. S. ^{[1
]}

机构：

[1] Int Univ Bremen, Sch Engn & Sci, D-28725 Bremen, Germany

[2] Univ Osnabruck, Fachbereich Phys, D-49074 Osnabruck, Germany

来源：

PHYSICAL REVIEW B | 2006年 / 74卷 / 04期

关键词：

D O I：

10.1103/PhysRevB.74.041402

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A combined study of scanning tunneling microscopy (STM) and density functional theory (DFT) reveals that 3,4,9,10-perylene-tetracarboxylic-dianhydride (PTCDA) adsorbs on Ag(111) at bridge sites in two nonequivalent orientations, one nearly aligned with the [10 (1) over bar] substrate axis and the other 18 degrees misaligned. Site-specific spectroscopy reveals that molecules in the two configurations exhibit subtle differences in their electronic structure. DFT-based STM simulations trace these back to the influence of distinct local adsorption geometries on the chemical molecule-substrate and molecule-molecule interactions.

引用

页数：4

共 50 条

[21] Site-specific effects of strength training on bone structure and geometry of ultradistal radius in postmenopausal women
Adami, S
Gatti, D
Braga, V
Bianchini, D
Rossini, M
JOURNAL OF BONE AND MINERAL RESEARCH, 1999, 14 (01) : 120 - 124
[22] Site-specific metal and ligand substitutions in a microporous Mn2+-based metal-organic framework
Huxley, Michael
Coghlan, Campbell J.
Burgun, Alexandre
Tarzia, Andrew
Sumida, Kenji
Sumby, Christopher J.
Doonan, Christian J.
DALTON TRANSACTIONS, 2016, 45 (10) : 4431 - 4438
[23] Site-Specific Organic/Metal Interaction Revealed from Shockley-Type Interface State
Yamane, Hiroyuki
Kosugi, Nobuhiro
JOURNAL OF PHYSICAL CHEMISTRY C, 2016, 120 (42): : 24307 - 24313
[24] Site-specific anisotropic assembly of amorphous mesoporous subunits on crystalline metal-organic framework
Liu, Minchao
Shang, Cheng
Zhao, Tiancong
Yu, Hongyue
Kou, Yufang
Lv, Zirui
Hou, Mengmeng
Zhang, Fan
Li, Qiaowei
Zhao, Dongyuan
Li, Xiaomin
NATURE COMMUNICATIONS, 2023, 14 (01)
[25] The Adsorption Geometry and Electronic Structure of Organic Dye Molecule on TiO2(101) Surface from First Principles Calculations
Niu, Mang
2016 INTERNATIONAL CONFERENCE ON BIOMATERIALS, NANOMATERIALS AND COMPOSITE MATERIALS (CBNCM 2016), 2017, 88
[26] Adsorption process, atomic geometry, electronic structure and stability of Si(001)/Te surface
Miwa, RH
Ferraz, AC
SURFACE SCIENCE, 2000, 449 (1-3) : 180 - 190
[27] Confinement of Ultrasmall Bimetallic Nanoparticles in Conductive Metal-Organic Frameworks via Site-Specific Nucleation
Park, Chungseong
Koo, Won-Tae
Chong, Sanggyu
Shin, Hamin
Kim, Yoon Hwa
Cho, Hee-Jin
Jang, Ji-Soo
Kim, Dong-Ha
Lee, Jiyoung
Park, Seyeon
Ko, Jaehyun
Kim, Jihan
Kim, Il-Doo
ADVANCED MATERIALS, 2021, 33 (38)
[28] Direct observation of the site-specific valence electronic structure at SiO2/Si(111) interface
Yamashita, Y.
Yamamoto, S.
Mukai, K.
Yoshinobu, J.
Harada, Y.
Tokushima, T.
Takeuchi, T.
Takata, Y.
Shin, S.
Akagi, K.
Tsuneyuki, S.
E-JOURNAL OF SURFACE SCIENCE AND NANOTECHNOLOGY, 2006, 4 : 280 - 284
[29] Site-specific electronic structure of the RBa2Cu3O7-y family
Merz, M
Gerhold, S
Nücker, N
Kuntscher, CA
Burbulla, B
Schweiss, P
Schuppler, S
Chakarian, V
Freeland, J
Idzerda, YU
Kläser, M
Müller-Vogt, G
Wolf, T
PHYSICAL REVIEW B, 1999, 60 (13): : 9317 - 9320
[30] Site-specific electronic and geometric interface structure of Co-tetraphenyl-porphyrin layers on Ag(111)
Auwaerter, Willi
Seufert, Knud
Klappenberger, Florian
Reichert, Joachim
Weber-Bargioni, Alexander
Verdini, Alberto
Cvetko, Dean
Dell'Angela, Martina
Floreano, Luca
Cossaro, Albano
Bavdek, Gregor
Morgante, Alberto
Seitsonen, Ari P.
Barth, Johannes V.
PHYSICAL REVIEW B, 2010, 81 (24)

← 1 2 3 4 5 →