Potassium(I)thallium(I) heterometallic 3D polymeric mixed-anions compound, succinate-nitrate [K2Tl([μ-C4H4O4)(μ-NO3)]n

被引：11
|
作者：
Askarinejad, Azadeh [1 ]
Morsali, Ali [1 ]
机构：
[1] Tarbiat Modares Univ, Dept Chem, Sch Sci, Tehran, Iran
来源：
INORGANICA CHIMICA ACTA | 2006年 / 359卷 / 10期
关键词：
potassium(I); thallium(I); heterometallic; lone pair; succinate; nitrate;
D O I：
10.1016/j.ica.2006.03.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A three-dimensional polymeric K(I)T1(I) heterometallic compound [K(2)T1(mu-C4H4O4)(mu-NO3)](n), with mixes succinate and nitrate ligands, has been synthesized and characterized. Its single-crystal X-ray structure shows two types of K+-ions with coordination numbers of seven and eight and one T1(+)-ion with a coordination number of five. However, the arrangement of O-atoms for T1(I) suggests a gap or hole in the coordination geometry around this atom. This 'hole' is possibly occupied by a stereochemically 'active' electron lone pair of thallium atoms. Two hydrogen atoms of succinate situated 3.26 angstrom above the proposed site on the lone pair of T1(I) is oriented in such a way that it might be thought to be forming weak T1-Lp center dot center dot center dot H-C hydrogen bond or agostic interactions, thus attaining of environment T1O(5)H(2). (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：3379 / 3383
页数：5
相关论文
共 50 条
  • [31] The 3D supramolecular compound {[Cu2(L-val)2(4,4′-bipy)(H2O)2](NO3)2}n (L-val = L-valine anion, 4,4′-bipy=4,4′-bipyridine)
    Lou, Benyong
    Huang, Xiaodong
    Lin, Xiangchao
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (03): : 372 - 374
  • [32] Hydrothermal synthesis and characterization of a new 3D vanadium(III) phosphite (C4H8N2H4)0.5(C4H8N2H3)[V4(HPO3)7(H2O)3]1.5H2O
    Shi, SH
    Wang, L
    Yuan, HM
    Li, GH
    Xu, JN
    Zhu, GS
    Song, TY
    Qiu, SL
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (11) : 4183 - 4187
  • [33] Crystal structure of tatrakis(1,10-phenanthroline)-fumaratodilead(II) nitrate, [Pb2(C12H8N2)4(C4H2O4)]NO3)2
    Niu, Yan-Ling
    Li, Xiu-Mei
    Wang, Qing-Wei
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (01): : 164 - 166
  • [34] Crystal structure of poly[tetrakis(μ3-2-aminonicotinato-K3N,O,O′)-(μ2-oxalato-K4O,O′:O",O′")-(μ4-oxalato-K6N:N′:O,O′:O",O′")dicopper(I)-disamarium(III)], [SmCu(C6N2H5O2)2(C2O4)] n
    Zhou, Wei-Wei
    Zhao, Wang
    Wang, Jing
    Song, Ming-Jun
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2023, 238 (01): : 39 - 41
  • [35] 4-DIMETHYLAMINO-3-NITROCINNAMIC ACID, C11H12N2O4 (I), AND 1-(4-DIMETHYLAMINOCINNAMOYL)IMIDAZOLE, C14H15N3O (II)
    HUBER, CP
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1985, 41 (JUL) : 1076 - 1079
  • [36] Crystal structure of diethylenetriammonium silver(I) di(4-nitrobenzoate) monohydrate, [Ag(C4H14N3)](C7H4NO4)2•H2O
    Zhu, HL
    Shao, SC
    Yang, S
    Qiu, XY
    Ma, JL
    Fun, HK
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2003, 218 (04): : 511 - 512
  • [37] Study on Novel Structure of Potassium Piperazine Complex: C4H10N2K3O2
    Liu, Hai-Xing
    Xiao, Jing-Zhong
    Guo, Huan-Mei
    Ye, Kai-Qi
    Zeng, Guang
    Tai, Xi-Shi
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (14) : 8229 - 8230
  • [38] KOMPLEKSOOBRAZOVANIE I SOSTAV OBRAZUYUSHCHIKHSYA OSADKOV V SISTEMAKH - NISO4-K3FE(CN)6-H2O, KJ-HG(NO3)2-H2O I ALBR3-C5H5N-C6H6
    GORENBEIN, EY
    FOMINSKAYA, AA
    ZHURNAL NEORGANICHESKOI KHIMII, 1963, 8 (06): : 1473 - 1478
  • [39] Crystal structure of nitratobis[2-(2-methylimidazol)-4,4,5,5-tetramethyl-2-imidazoline-1-oxyl]copper(II) nitrate, [Cu(C11H17N4O)2(NO3)](NO3)
    Ju, Feng-Yang
    Yang, Li
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2010, 225 (04): : 768 - 770
  • [40] Crystal structure of nitratobis(1,10-phenanthroline-N,N′)cobalt(II) nitrate tetrahydrate, [Co(C12H8N2)2(NO3)]NO3 • 4H2O
    Zheng, YQ
    Zhang, HL
    Lin, JL
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2002, 217 (01): : 67 - 68
12345