Cooling crystallization of 1,1-diamino-2,2-dinitroethylene

被引：0

作者：

Kim, Jae-Kyeong ^{[1
]}

Kim, Jun-Woo ^{[1
]}

Kim, Hyoun-Soo ^{[2
]}

Koo, Kee-Kahb ^{[1
]}

机构：

[1] Sogang Univ, Seoul 121742, South Korea

[2] Agcy Def Dev, Daejeon 305600, South Korea

来源：

NEW TRENDS IN RESEARCH OF ENERGETIC MATERIALS, PTS I & II, 13TH SEMINAR | 2010年

关键词：

cooling; crystallization; 1,1-diamino-2,2-dinitroethylene;

D O I：

暂无

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

For manipulating crystal quality of 1,1-dianzino-2,2-dinitroethylene (DADNE), experiments on the cooling crystallization of DADNE were made as a function of cosol-vents(solvent/anti-solvent mixtures), DADNE concentrations, cooling rates and stirring speeds. When N-methyl-2-pyrrolidone (NMP) and dimethylformamide (DMF) were used as a single solvent, DADNE crystals were shown to be agglomerates with needles or platelets and their yields were about 15-30 %. On the other hand, when cosolvents with water(DMAc+H2O) were used, polyhedron-shaped DADNE crystals with size of 100-200 mu m and yields of 70-80 % were obtained.

引用

页码：518 / 522

页数：5

共 50 条

[31] Configuration and Stability of 1,1-Diamino-2,2-dinitroethylene (FOX-7) Embedded in Graphene
Wang, Yan-qun
Wang, Gui-xiang
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2016, 37 (10): : 1571 - 1576
[32] 1,1-diamino-2,2-dinitroethylene:: a novel energetic material with infinite layers in two dimensions
Bemm, U
Östmark, H
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1998, 54 : 1997 - 1999
[33] Thermochemical properties, thermal behavior and decomposition mechanism of 1,1-diamino-2,2-dinitroethylene (DADE)
Gao, HX
Zhao, FQ
Hu, RZ
Pan, Q
Wang, BZ
Yang, XW
Gao, Y
Gao, SL
Shi, QZ
CHINESE JOURNAL OF CHEMISTRY, 2006, 24 (02) : 177 - 181
[34] Synthesis, characterization and thermolysis of 1,1-diamino-2,2-dinitroethylene (FOX-7) and its salts
Anniyappan, M.
Talawar, M. B.
Gore, G. M.
Venugopalan, S.
Gandhe, B. R.
JOURNAL OF HAZARDOUS MATERIALS, 2006, 137 (02) : 812 - 819
[35] Initial decomposition pathways of 1,1-diamino-2,2-dinitroethylene (α-FOX-7) in the condensed phase
Yadav, Komal
Luo, Yuheng
Kaiser, Ralf I.
Sun, Rui
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2024, 26 (15) : 11395 - 11405
[36] Thermochemical properties of 1,1-diamino-2,2-dinitroethylene (FOX-7) in dimethyl sulfoxide (DMSO)
Xing Xiao-Ling
Xue Liang
Zhao Feng-Qi
Gao Hong-Xu
Hu Rong-Zu
THERMOCHIMICA ACTA, 2009, 491 (1-2) : 35 - 38
[37] Kinetics of Reversible Polymorphic Transition in Energetic Materials. Phase Transitions α → β and β → α in 1,1-Diamino-2,2-Dinitroethylene
Zakharov, V. V.
Chukanov, N. V.
Chervonnyi, A. D.
Vozchikova, S. A.
Korsounskii, B. L.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 8 (06) : 822 - 828
[38] Kinetics of reversible polymorphic transition in energetic materials. Phase transitions α → β and β → α in 1,1-diamino-2,2-dinitroethylene
V. V. Zakharov
N. V. Chukanov
A. D. Chervonnyi
S. A. Vozchikova
B. L. Korsounskii
Russian Journal of Physical Chemistry B, 2014, 8 : 822 - 828
[39] The new role of 1,1-diamino-2,2-dinitroethylene (FOX-7): two unexpected reactions
Zhou, Tianhong
Li, Yanfeng
Xu, Kangzhen
Song, Jirong
Zhao, Fengqi
NEW JOURNAL OF CHEMISTRY, 2017, 41 (01) : 168 - 176
[40] Ultraviolet-Initiated Decomposition of Solid 1,1-Diamino-2,2-dinitroethylene (FOX-7)
Turner, Andrew M.
Marks, Joshua H.
Lechner, Jasmin T.
Klapotke, Thomas M.
Sun, Rui
Kaiser, Ralf I.
JOURNAL OF PHYSICAL CHEMISTRY A, 2023, 127 (37): : 7707 - 7717

← 1 2 3 4 5 →