Clusters containing metal-metal bonds linking high- and low-valent metal centres:: synthesis and structure of Ru3(CO)12{Mo(NAr)2}

被引：2
|
作者：
Ali, S
Carty, AJ
Deeming, AJ
Enright, GD
Hogarth, G
机构：
[1] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
[2] UCL, Dept Chem, London WC1H 0AJ, England
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 02期
关键词：
D O I：
10.1039/a908982i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Room temperature reaction of K(2)[Ru(3)(CO)(11)] with the molybdenum(VI) bis(imido) complexes Mo(NAr)(2)Cl(2)(dme) (Ar = C(6)H(3)X(2)-2,6; X = Me, Pr(i), Cl; dme = 1,2-dimethoxyethane) affords new high-low valent clusters Ru(3)(CO)(12){Mo(NAr)(2)} which adopt a butterfly arrangement of metal centres with [Ru(3)(CO)(12)](2-) acting as a ligand at a molybdenum(VI) centre.
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页码：123 / 124
页数：2
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