An Efficient Gram Scale Synthesis of Aryl Iodides from Aryl Diazofluoroborates in Water Under Mild Conditions

被引：6

作者：

Gholap, Somnath S. ^{[1
]}

机构：

[1] Padmashri Vikhe Patil Coll, Post Grad Dept & Res Ctr, Tal Rahata 413713, MS, India

来源：

LETTERS IN ORGANIC CHEMISTRY | 2018年 / 15卷 / 07期

关键词：

Aryl iodides; diazofluoroborates; potassium iodide; quantitative protocol; transition metal-free; organic; ARYLDIAZONIUM TETRAFLUOROBORATE SALTS; DIAZONIUM TETRAFLUOROBORATE; AROMATIC IODINATION; GREEN; CHEMISTRY; CHLORIDES; CATALYST; AMINES; ACID;

D O I：

10.2174/1570178614666170907120329

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Transition metal-free synthesis of synthetically valuable aryl iodides from aryl diazofluroborates in water under mild conditions has been described. Majority of synthesized aryl iodides are obtained in quantitative yields (>99 %) under present reaction conditions. The structural effects due to the substituents present on aryl diazofluoroborates did not show any satisfactory effect on the yields of the aryl iodides. Hence, the methodology presented here was found to be adventitious for the quantitative production of synthetically valuable aryl iodides.

引用

页码：594 / 599

页数：6

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