pH controlled emission of ruthenium(II)-tris-bipyridine complexes

被引：2
|
作者：
De Cola, L
Prodi, L
Zaccheroni, N
König, B
机构：
[1] Univ Amsterdam, Mol Photon Grp, IMC, NL-1018 WV Amsterdam, Netherlands
[2] Dipartimento Chim G Ciamician, Photochem & Supramol Chem Grp, I-40126 Bologna, Italy
[3] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany
来源：
INORGANICA CHIMICA ACTA | 2002年 / 336卷
关键词：
coordination chemistry; photochemistry; N-ligands; ruthenium; UV-Vis spectroscopy;
D O I：
10.1016/S0020-1693(02)00729-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ruthenium tris-2,2'-bipyridine complexes 1, 2 and 3 have additional non-coordinated basic pyridine or bipyridine moieties within their structures. Upon protonation they reversibly become suitable acceptor sites for intramolecular photoinduced electron transfer by which the ruthenium tris-2,2'-bipyridine emission is quenched. The pH dependent emission was studied in organic solvents and water. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
下载
收藏
页码：1 / 7
页数：7
相关论文
共 50 条
  • [41] Mechanism of the Quenching of the Tris(bipyridine)ruthenium(II) Emission by Persulfate: Implications for Photoinduced Oxidation Reactions
    Lewandowska-Andralojc, A.
    Polyansky, D. E.
    JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 117 (40): : 10311 - 10319
  • [42] The first asymmetric synthesis of chiral ruthenium tris(bipyridine) from racemic ruthenium bis(bipyridine) complexes
    Hesek, D
    Inoue, Y
    Ishida, H
    Everitt, SRL
    Drew, MGB
    TETRAHEDRON LETTERS, 2000, 41 (15) : 2617 - 2620
  • [43] Synthesis and photochemical properties of a new substituted phenol covalently linked to ruthenium (II) tris-bipyridine containing four ester groups as sensitizer
    Shi, F
    Li, HY
    Peng, XJ
    Zhang, R
    Chen, XQ
    Fan, JL
    Sun, LC
    CHINESE CHEMICAL LETTERS, 2004, 15 (12) : 1407 - 1410
  • [44] IMMOBILIZED TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) COMPLEXES AS PHOTOSENSITIZERS OF WATER PHOTOLYSIS
    NUSSBAUMER, W
    GRUBER, H
    GREBER, G
    MAKROMOLEKULARE CHEMIE-MACROMOLECULAR CHEMISTRY AND PHYSICS, 1988, 189 (05): : 1027 - 1033
  • [45] TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) SENSITIZED REACTIONS OF SOME OXALATO COMPLEXES
    DEMAS, JN
    ADAMSON, AW
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (16) : 5159 - 5168
  • [46] UPON THE SYNTHESIS OF TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II) SALTS AND RELATED COMPLEXES
    ANDERSON, S
    SEDDON, KR
    JOURNAL OF CHEMICAL RESEARCH-S, 1979, (02): : 75 - &
  • [47] Photochemical reactivity of iron(III)-doped ruthenium(II)-tris-bipyridine/titanium dioxide zeolite Y photocatalysts at high substrate concentrations
    Pokhrel, Megh Raj
    Janik, Katharine
    Bossmann, Stefan H.
    JOURNAL OF ADVANCED OXIDATION TECHNOLOGIES, 2008, 11 (02) : 348 - 353
  • [48] Photoisomerisation in Aminoazobenzene-Substituted Ruthenium(II) Tris(bipyridine) Complexes: Influence of the Conjugation Pathway
    Amar, Anissa
    Savel, Paul
    Akdas-Kilig, Huriye
    Katan, Claudine
    Meghezzi, Hacene
    Boucekkine, Abdou
    Malval, Jean-Pierre
    Fillaut, Jean-Luc
    CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (22) : 8262 - 8270
  • [49] The isolation and secondary functionalisation of fac-tris-2,2′-bipyridine complexes of ruthenium(II)
    Fletcher, NC
    Nieuwenhuyzen, M
    Prabarahan, R
    Wilson, A
    CHEMICAL COMMUNICATIONS, 2002, (11) : 1188 - 1189
  • [50] Selective protein-surface sensing using ruthenium (II) tris-(bipyridine) complexes
    Wilson, Andrew John
    Ashcroft, Alison
    Muldoon, James
    Filby, Maria
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 239
12345