The X-ray Crystal Structure of a Cuprate-Carbonyl π-Complex

被引：13
|
作者：
Bertz, Steven H. [1 ]
Hardin, Richard A. [1 ]
Heavey, Thomas J. [1 ]
Ogle, Craig A. [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Charlotte, NC 28223 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 39期
基金：
美国国家科学基金会;
关键词：
cuprates; fluorenone; NMR spectroscopy; X-ray diffraction; -complexes; RAPID-INJECTION NMR; LITHIUM DIMETHYLCUPRATE(I); COPPER(III) INTERMEDIATE; GILMAN REAGENT; CHEMISTRY; TETRAHYDROFURAN; 9-FLUORENONE; REACTIVITY; ME2CULI; KETONES;
D O I：
10.1002/anie.201303783
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Why is it π? The first X-ray crystal structure of a cuprate-carbonyl π-complex has been obtained for the intermediate prepared from Me 2CuLi and fluorenone (see scheme). It is also the first structure of a π-complex between an organocuprate and a double bond of any kind. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：10250 / 10252
页数：3
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