Porphyrin-Catalyzed Oxidation of N-Substituted Tetrahydroisoquinolines to Dihydroisoquinolones

被引：8

作者：

Li, Ao ^{[1
]}

Pan, Bin ^{[2
]}

Mu, Chao ^{[1
]}

Wang, Na ^{[2
]}

Li, Yu-Long ^{[1
]}

Ouyang, Qin ^{[2
]}

机构：

[1] Sichuan Univ Sci & Engn, Coll Chem & Environm Engn, Zigong 643000, Peoples R China

[2] Third Mil Med Univ, Coll Pharm, Chongqing 400038, Peoples R China

来源：

SYNLETT | 2021年 / 32卷 / 07期

基金：

国家重点研发计划;

关键词：

photocatalysis; oxidation; porphyrins; zinc catalysis; dihydroisoquinolones; SUPPORTED GOLD NANOPARTICLES; AEROBIC OXIDATION; BENZYLIC AMINES; CYCLIC AMINES; ADIPIC ACID; IN-VITRO; CYCLIZATION; HEMOGLOBIN; ASCORBATE; LACTAMS;

D O I：

10.1055/a-1345-3491

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A visible-light-induced direct alpha-oxygenation of N-substituted 1,2,3,4-tetrahydroisoquinoline derivatives has been successfully developed. Tetraphenylporphyrinatozinc(II) has been identified as an effective and inexpensive photocatalyst for this transformation with a wide range of substrates. This protocol provides a convenient route to the desired products in moderate to good yields at room temperature under air.

引用

页码：679 / 684

页数：6

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