A metal-free and all-organic redox flow battery with polythiophene as the electroactive species

被引：90
|
作者：
Oh, S. H. [1 ,2 ]
Lee, C. -W. [1 ]
Chun, D. H. [3 ]
Jeon, J. -D. [1 ]
Shim, J. [1 ]
Shin, K. H. [1 ]
Yang, J. H. [1 ]
机构：
[1] Korea Inst Energy Res, Energy Storage Lab, Taejon 305343, South Korea
[2] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
[3] Korea Inst Energy Res, Clean Fuel Lab, Taejon 305343, South Korea
来源：
JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 47期
基金：
新加坡国家研究基金会;
关键词：
ENERGY-STORAGE; ELECTROLYTES; CAPACITORS; PROGRESS; BROMINE; ANODE;
D O I：
10.1039/c4ta04730c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A metal-free and all-organic redox flow battery is proposed and investigated. It employs polythiophene microparticles dispersed in electrolyte solutions as the redox couple and does not depend on limited metal resources. It shows a high cell potential and stable charge/discharge performance with a high energy efficiency of 60.9%.
引用
收藏
页码：19994 / 19998
页数：5
相关论文
共 50 条
  • [41] An All-Organic battery with 2.8 V output voltage
    Jiang, Shangxu
    Li, Wenbiao
    Xie, Yuan
    Yan, Xiaoqing
    Zhang, Kai
    Jia, Zhongfan
    CHEMICAL ENGINEERING JOURNAL, 2022, 434
  • [42] High-efficiency metal-free CO2 mineralization battery using organic redox catalysts
    Wang, Yunpeng
    Liu, Tao
    Cheng, Chun
    Xie, Yachen
    Lan, Cheng
    Jiang, Wenchuan
    Zhao, Zhiyu
    Zhai, Shuo
    Li, Yiri
    Wu, Yifan
    Xie, Heping
    CHEMICAL ENGINEERING JOURNAL, 2024, 496
  • [43] A Symmetric All-Organic Proton Battery in Mild Electrolyte
    Tie, Zhiwei
    Deng, Shenzhen
    Cao, Hongmei
    Yao, Minjie
    Niu, Zhiqiang
    Chen, Jun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (08)
  • [44] A polyimide based all-organic sodium ion battery
    Banda, Harish
    Damien, Dijo
    Nagarajan, Kalaivanan
    Hariharan, Mahesh
    Shaijumon, Manikoth M.
    JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (19) : 10453 - 10458
  • [45] A new aqueous all-organic flow battery with high cell voltage in acidic electrolytes
    Leung, P.
    Martin, T.
    Xu, Q.
    Flox, C.
    Mohamad, M. R.
    Palma, J.
    Rodchanarowan, A.
    Zhu, X.
    Xing, W. W.
    Shah, A. A.
    APPLIED ENERGY, 2021, 282
  • [46] An All-Organic Aqueous Battery Powered by Adsorbed Quinone
    Xu, Yuan
    Zheng, Yiting
    Wang, Congcheng
    Chen, Qing
    ACS APPLIED MATERIALS & INTERFACES, 2019, 11 (26) : 23222 - 23228
  • [47] Advances in organic electroactive species for enhancing the performance of all-aqueous redox flow batteries in electrochemical energy storage
    Pileri, Francesco
    Freitas, Williane da Silva
    D'Epifanio, Alessandra
    Mecheri, Barbara
    JOURNAL OF ENERGY STORAGE, 2025, 113
  • [48] Mechanism-Based Design of a High-Potential Catholyte Enables a 3.2 V All-Organic Nonaqueous Redox Flow Battery
    Yan, Yichao
    Robinson, Sophia G.
    Sigman, Matthew S.
    Sanford, Melanie S.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (38) : 15301 - 15306
  • [49] Review on Redox-Active Organic Compounds for All-Organic Batteries
    Yu, Zehao
    Wang, Yinxu
    Luo, Zhiqiang
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2024, 63 (22) : 9619 - 9630
  • [50] A 1.9-V all-organic battery-supercapacitor hybrid device with high rate capability and wide temperature tolerance in a metal-free water-in-salt electrolyte
    Tsai, Hsiang-Hsi
    Lin, Tzu-Jen
    Vedhanarayanan, Balaraman
    Tsai, Cheng-Che
    Chen, Ting-Yu
    Ji, Xiaobo
    Lin, Tsung-Wu
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2022, 612 : 76 - 87
12345