Quantitative analysis of chemoconvection patterns in the methylene-blue -: Glucose system

被引:13
|
作者
Pons, AJ
Sagués, F
Bees, MA
Sorensen, PG
机构
[1] Univ Copenhagen, HC Orsted Inst, Dept Chem, DK-2100 Copenhagen, Denmark
[2] Univ Barcelona, Dept Quim Fis, E-08028 Barcelona, Spain
[3] Univ Surrey, Dept Math & Stat, Guildford GU2 7XH, Surrey, England
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2002年 / 106卷 / 29期
关键词
D O I
10.1021/jp014346n
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report a quantitative analysis of a series of chemically induced convection patterns for the methylene-blue-glucose system at different experimental conditions. The objective of the study is to get some quantitative knowledge of the phenomenon (for example, the characteristic wavelength and the characteristic time for the pattern to appear). We focus our attention on the initial stages of the pattern appearance just after the instability and at some aspects of the general behavior of the complete pattern evolution. We analyze the effect on length and time scales of the patterns obtained when varying the initial values of three different experimental parameters (viscosity, pH, and layer depth). The results obtained in the "linear growth" regime reproduce the qualitative trends extracted from the linear stability analysis of a theoretical model subject to a pseudo-steady-state approximation.
引用
收藏
页码:7252 / 7259
页数:8
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