(6S)-Methyl-L-swainsonine [(1R, 2S, 6S, 8S, 8aS)-6-methyloctahydroindolizine-1,2,8-triol]

被引：2

作者：

Hakansson, Anders E.

Horne, Graeme

Fleet, George W. J.

Watkin, David J.

机构：

[1] Univ Oxford, Chem Res Lab, Dept Organ Chem, Oxford OX1 3TA, England

[2] Univ Oxford, Chem Res Lab, Dept Chem Crystallog, Oxford OX1 3TA, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2007年 / 63卷

关键词：

D O I：

10.1107/S1600536806052111

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

(6S)-Methyl-L-swainsonine, C9H17NO3, together with the 6R-epimer, was formed in a synthetic sequence in which there was an ambiguity in configuration at position C-6. This ambiguity was resolved by establishing the relative stereochemistry of the title compound by X-ray crystallographic analysis. The absolute configuration was determined by the use of D-glycero-D-gulo-heptono-1,4-lactone as the starting material.

引用

页码：O210 / O212

页数：3

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