Peculiarities in the Director Reorientation and the NMR Spectra Evolution in a Nematic Liquid Crystals under the Effect of Crossed Electric and Magnetic Fields

被引:4
|
作者
Zakharov, Alex, V [1 ]
Sliwa, Izabela [2 ]
机构
[1] Russian Acad Sci, St Petersburg Inst Machine Sci, St Petersburg 199178, Russia
[2] Poznan Univ Econ & Business, Dept Math Econ, Al Niepodleglosci 10, PL-61875 Poznan, Poland
来源
CRYSTALS | 2019年 / 9卷 / 05期
关键词
liquid crystals; NMR; hydrodynamics of liquid crystals; 61; 30; Cz; 65; 40; De; ORIENTATIONAL ORDER; ANGULAR-DEPENDENCE; DYNAMICS;
D O I
10.3390/cryst9050262
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The illustrative description of the field-induced peculiarities of the director reorientation in the microsized nematic volumes under the effect of crossed magnetic B and electric E fields have been proposed. The most interesting feature of such configuration is that the nematic phase becomes unstable after applying the strong E. The theoretical analysis of the reorientational dynamics of the director field provides an evidence for the appearance of the spatially periodic patterns in response to applied large E directed at an angle a to B. The feature of this approach is that the periodic distortions arise spontaneously from a homogeneously aligned nematic sample that ultimately induces a faster response than in the uniform mode. The nonuniform rotational modes involve additional internal elastic distortions of the conservative nematic system and, as a result, these deformations decrease of the viscous contribution Uvis to the total energy U of the nematic phase. In turn, that decreasing of Uvis leads to decrease of the effective rotational viscosity coefficient g eff (a). That is, a lower value of g eff (a), which is less than one in the bulk nematic phase, gives the less relaxation time t on (a) g eff (a), when a is bigger than the threshold value a th. The results obtained by Deuterium NMR spectroscopy confirm theoretically obtained dependencies of t on (a) on alpha.
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页数:23
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