Poly(exTTF): A Novel Redox-Active Polymer as Active Material for Li-Organic Batteries

被引：35
|
作者：
Haeupler, Bernhard [1 ,2 ]
Burges, Rene [1 ,2 ]
Friebe, Christian [1 ,2 ]
Janoschka, Tobias [1 ,2 ]
Schmidt, Daniel [1 ,2 ]
Wild, Andreas [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ]
机构：
[1] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany
[2] Univ Jena, JCSM, D-07743 Jena, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2014年 / 35卷 / 15期
关键词：
organic battery; polymer; redox chemistry; exTTF; RECHARGEABLE LITHIUM BATTERIES; CHARGE/DISCHARGE PROPERTIES; ELECTRODE MATERIALS; RADICAL BATTERY; HIGH-CAPACITY; DISCHARGE; CHARGE;
D O I：
10.1002/marc.201400167
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The first polymer bearing exTTF units intended for the use in electrical charge storage is presented. The polymer undergoes a redox reaction involving two electrons at -0.20 V vs Fc/Fc(+) and is applied as active cathode material in a Li-organic battery. The received coin cells feature a theoretical capacity of 132 mAh g(-1), a cell potential of 3.5 V, and a lifetime exceeding more than 250 cycles.
引用
收藏
页码：1367 / 1371
页数：5
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