Poly(exTTF): A Novel Redox-Active Polymer as Active Material for Li-Organic Batteries

被引：35
|
作者：
Haeupler, Bernhard [1 ,2 ]
Burges, Rene [1 ,2 ]
Friebe, Christian [1 ,2 ]
Janoschka, Tobias [1 ,2 ]
Schmidt, Daniel [1 ,2 ]
Wild, Andreas [1 ,2 ]
Schubert, Ulrich S. [1 ,2 ]
机构：
[1] Univ Jena, Lab Organ & Macromol Chem, D-07743 Jena, Germany
[2] Univ Jena, JCSM, D-07743 Jena, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2014年 / 35卷 / 15期
关键词：
organic battery; polymer; redox chemistry; exTTF; RECHARGEABLE LITHIUM BATTERIES; CHARGE/DISCHARGE PROPERTIES; ELECTRODE MATERIALS; RADICAL BATTERY; HIGH-CAPACITY; DISCHARGE; CHARGE;
D O I：
10.1002/marc.201400167
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The first polymer bearing exTTF units intended for the use in electrical charge storage is presented. The polymer undergoes a redox reaction involving two electrons at -0.20 V vs Fc/Fc(+) and is applied as active cathode material in a Li-organic battery. The received coin cells feature a theoretical capacity of 132 mAh g(-1), a cell potential of 3.5 V, and a lifetime exceeding more than 250 cycles.
引用
收藏
页码：1367 / 1371
页数：5
相关论文
共 50 条
  • [1] Exploration of Li-Organic Batteries Using Hexaphyrin as an Active Cathode Material
    Shin, Ji-Young
    Zhang, Zhongyue
    Awaga, Kunio
    Shinokubo, Hiroshi
    MOLECULES, 2019, 24 (13):
  • [2] Redox-Active Macrocycles for Organic Rechargeable Batteries
    Kim, Dong Jun
    Hermann, Keith R.
    Prokofjevs, Aleksandrs
    Otley, Michael T.
    Pezzato, Cristian
    Owczarek, Magdalena
    Stoddart, J. Fraser
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (19) : 6635 - 6643
  • [3] Poly(boron-dipyrromethene)-A Redox-Active Polymer Class for Polymer Redox-Flow Batteries
    Winsberg, Jan
    Hagemann, Tino
    Muench, Simon
    Friebe, Christian
    Haeupler, Bernhard
    Janoschka, Tobias
    Morgenstern, Sabine
    Hager, Martin D.
    Schubert, Ulrich S.
    CHEMISTRY OF MATERIALS, 2016, 28 (10) : 3401 - 3405
  • [4] Redox-Active Functionalized Graphene Nanoribbons as Electrode Material for Li-Ion Batteries
    Pirnat, Klemen
    Bitenc, Jan
    Jerman, Ivan
    Dominko, Robert
    Genorio, Bostjan
    CHEMELECTROCHEM, 2014, 1 (12): : 2131 - 2137
  • [5] Phosphazene-cored star polymer bearing redox-active side groups as a cathode-active material in Li-ion batteries
    Aydin, Muhammet
    Gorur, Mesut
    Yilmaz, Faruk
    REACTIVE & FUNCTIONAL POLYMERS, 2016, 102 : 11 - 19
  • [6] Organic redox-active molecules for alkaline aqueous redox flow batteries
    Lu, Biao
    Yu, Kaifeng
    Shao, Weide
    Ji, Ya
    Zhang, Feifei
    CURRENT OPINION IN GREEN AND SUSTAINABLE CHEMISTRY, 2024, 47
  • [7] Hydrophilic Organic Redox-Active Polymer Nanoparticles for Higher Energy Density Flow Batteries
    Hatakeyama-Sato, Kan
    Nagano, Takashi
    Noguchi, Shiori
    Sugai, Yota
    Du, Jie
    Nishide, Hiroyuki
    Oyaizu, Kenichi
    ACS APPLIED POLYMER MATERIALS, 2019, 1 (02): : 188 - +
  • [8] Solubility and Stability of Redox-Active Organic Molecules in Redox Flow Batteries
    Singh, Vikram
    Byon, Hye Ryung
    ACS APPLIED ENERGY MATERIALS, 2023, 7 (18): : 7562 - 7575
  • [9] Tailoring Polymer Polarity to Regulate Disulfide Accessibility in Redox-Active Particles for Organic Batteries
    Zhang, Hongyi
    Grocke, Garrett L.
    Rose, George
    Rowan, Stuart J.
    Patel, Shrayesh N.
    MACROMOLECULES, 2024, 57 (21) : 10410 - 10417
  • [10] Redox-active polypyrrole: Toward polymer-based batteries
    Song, Hyun-Kon
    Palmore, G. Tayhas R.
    ADVANCED MATERIALS, 2006, 18 (13) : 1764 - +
12345