Synthesis, Structure, and Thermal Properties of Tallium(I) N,N-cyclo-Pentamethylenedithiocarbamate [Tl2{S2CN(CH2)5}2]n: X-Ray Diffraction, 13C and 15N MAS NMR, and Thermal Analysis Studies (An Example of Complicated Structural Organization)

被引：4
|
作者：
Rodina, T. A. [1 ]
Ivanov, A. V. [2 ]
Bredyuk, O. A. [2 ]
Gerasimenko, A. V. [3 ]
机构：
[1] Amur State Univ, Blagoveshchensk 675027, Russia
[2] Russian Acad Sci, Far E Div, Inst Geol & Nat Management, Blagoveshchensk 675000, Russia
[3] Russian Acad Sci, Far E Div, Inst Chem, Vladivostok 690022, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 35卷 / 03期
基金：
俄罗斯基础研究基金会;
关键词：
CRYSTAL-STRUCTURE; CP/MAS NMR; CHEMICAL-SHIFTS; DIETHYLDITHIOCARBAMATE; SPECTROSCOPY; SOLIDS; ZINC;
D O I：
10.1134/S1070328409030026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Crystalline polynuclear thallium(I) N,N-cyclo-pentamethylenedithiocarbamate is synthesized by the preparative synthesis. According to the MAS NMR (C-13, N-15) data, its composition includes four structurally nonequivalent dithiocarbamate ligands. According to the X-ray diffraction data, the complex synthesized is a remarkable example for the self-organization of the chemical system with a simple composition into an unusually complicated structure. The latter includes three types of the nonequivalent binuclear molecules [Tl-2{S2CN(CH2)(5)}(2)] (I) performing various structural functions. Two of them (centrosymmetric) alternate and participate in infinite polymeric chain building. The third structural function (noncentrosymmetric) is associated with the joining of the polymeric chains into two-dimensional layers. Structurally nonequivalent binuclear molecules I are shown to be related as conformers. The study of the thermal properties of the complex shows that Tl2S is the final thermal destruction product.
引用
收藏
页码：170 / 178
页数：9
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