Synthesis of a new NASICON-type blue luminescent material

被引：34
|
作者：
Masui, Toshiyuki
Koyabu, Kazuhiko
Tamura, Shinji
Imanaka, Nobuhito
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] Handai Frontier Res Ctr, Suita, Osaka 5650871, Japan
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2006年 / 418卷 / 1-2期
关键词：
NASICON-type structure; phosphor; blue emission; divalent europium ion;
D O I：
10.1016/j.jallcom.2005.08.097
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new blue emitting phosphor, Eu0.5Zr2(PO4)(3), was synthesized for the first time by the solid-state reaction method. The sample developed in the present study has a stable NASICON-type rhombohedral structure, which consists of a three-dimensional network formed by PO4 tetrahedra sharing corners with ZrO6 octahedra in a single phase with high crystallinity. The photoluminescent emission spectrum shows typical emission from 4f(6)5d(1) to 47 of Eu2+, although the improvement of the luminescent property will be necessary by optimization of the preparation process and the modification of the particle morphology. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：73 / 76
页数：4
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