Synthesis of a novel acidic ionic liquid catalyst and its application for preparation of pyridines via a cooperative vinylogous anomeric-based oxidation

被引：7
|
作者：
Rahmati, Mohammad [1 ]
Habibi, Davood [1 ]
机构：
[1] Bu Ali Sina Univ, Dept Organ Chem, Fac Chem, Hamadan 6517838683, Hamadan, Iran
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2021年 / 47卷 / 04期
关键词：
Acidic ionic liquid; Anomeric-based oxidation; Cooperative vinylogous anomeric-based oxidation; Ionic liquid; Pyridine; POT MULTICOMPONENT SYNTHESIS; FRIEDEL-CRAFTS ALKYLATION; ASYMMETRIC ORGANOCATALYSIS; MAGNETIC NANOPARTICLES; HYDROGEN; DERIVATIVES; GLYCALS; 2-AMINO-4,6-DIPHENYLNICOTINONITRILES; ORTHOAMIDES; CHLORIDE;
D O I：
10.1007/s11164-020-04361-y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the current study, a novel acidic ionic liquid catalyst based on 8-hydroxyquinoline, namely 8,8 ',8 ''-([1,3,5-triazine-2,4,6-triyl]tris[oxy])tris(1-sulfoquinolin-1-ium)chloride (TTS), was designed and synthesized. The structure of the prepared acidic ionic liquid (AIL) was fully investigated by using Fourier transform infrared (FT-IR) spectroscopy, energy dispersive X-ray (EDX) analysis, thermogravimetric analysis/differential thermal analysis (TGA/DTA), (HNMR)-H-1, (CNMR)-C-13 and mass spectroscopy. Then, the catalytic performance of described AIL was successfully inspected toward the four-component synthesis of pyridine derivatives via a cooperative vinylogous anomeric-based oxidation. Graphic abstract Novel AIL (TTS) showed a very high efficiency in the synthesis of pyridines.
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页码：1643 / 1661
页数：19
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