Iron Corrole-catalyzed [4+2] Cycloaddition of Dienes and Aldehydes

被引：26
|
作者：
Kuwano, Toru [1 ]
Kurahashi, Takuya [1 ,2 ]
Matsubara, Seijiro [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan
[2] JST, ACT C, Kawaguchi, Saitama 3320012, Japan
来源：
CHEMISTRY LETTERS | 2013年 / 42卷 / 10期
关键词：
DIELS-ALDER REACTIONS; HIGH-VALENT METALLOPORPHYRIN; ELECTRONIC-STRUCTURE; PORPHYRIN; COMPLEXES; REARRANGEMENT; EPOXIDES; CYCLOISOMERIZATION; ROUTES;
D O I：
10.1246/cl.130672
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have developed cationic iron(IV) corrole-catalyzed formal hetero-Diels-Alder reaction of aldehydes with dienes, which opens the way for divergent synthesis of pyrans. The potential utility of the catalyst was also demonstrated by carrying out cycloaddition of alpha,beta-unsaturated aldehyde with a diene to give pyran selectively. Furthermore, the catalytic reactivity of iron corrole complex on the cycloaddition was determined by comparing that of iron porphyrin complex.
引用
收藏
页码：1241 / 1243
页数：3
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