Synthesis of Dibenzophosphole Oxides via Palladium-Catalyzed Intramolecular Direct Arylation Reactions of ortho-Halodiaryl-phosphine Oxides

被引：16

作者：

Cui, Yuming ^{[1
]}

Fu, Lingzi ^{[1
]}

Cao, Jian ^{[1
]}

Deng, Yuan ^{[1
]}

Jiang, Jianxiong ^{[1
]}

机构：

[1] Hangzhou Normal Univ, Key Lab Organosilicon Chem & Mat Technol, Minist Educ, Hangzhou 310012, Zhejiang, Peoples R China

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 06期

基金：

中国国家自然科学基金;

关键词：

catalysis; CH activation; direct arylation; heterofluorenes; palladium; H BOND ACTIVATION; COUPLING REACTIONS; ARYL CHLORIDES; HECK REACTIONS; FUNCTIONALIZATION; POLYMERS; SYSTEMS; POLY(2,7-DIBENZOSILOLE); POLY(2,7-CARBAZOLE); DIBENZOBOROLE;

D O I：

10.1002/adsc.201301081

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A palladium-catalyzed intramolecular direct arylation reaction was developed and two efficient one-pot sequential direct arylation/Suzuki-Miyaura coupling and intra/intermolecular direct arylation reations were also realized. The method provides a simple and straightforward procedure for the synthesis and further functionalization of dibenzophosphole oxides from easily accessible ortho-halodiarylphosphine oxides in good to excellent yields.

引用

页码：1217 / 1222

页数：6

共 50 条

[31] Asymmetric synthesis of chiral P-stereogenic triaryl phosphine oxides via Pd-catalyzed kinetic arylation of diaryl phosphine oxides
Zhang, Yong
He, Huan
Wang, Qiuyan
Cai, Qian
TETRAHEDRON LETTERS, 2016, 57 (48) : 5308 - 5311
[32] Palladium-Catalyzed Chemoselective Catellani ortho-Arylation Reactions and Their Applications in Natural Products Synthesis
Sui, Xianwei
Zhu, Rui
Gu, Zhenhua
SYNLETT, 2013, 24 (16) : 2023 - 2031
[33] Cascade Palladium-Catalyzed Direct Intramolecular Arylation/Alkene Isomerization Sequences: Synthesis of Indoles and Benzofurans
Yagoubi, Myriam
Cruz, Ana C. F.
Nichols, Paula L.
Elliott, Richard L.
Willis, Michael C.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (43) : 7958 - 7962
[34] Synthesis of α-hydroxyketones via palladium-catalyzed arylation of arylglyoxals
Li, Si-Yu
Ai, Zhao-Pin
Guo, Qi-Xiang
Wen, Wei
TETRAHEDRON, 2024, 166
[35] Microwave-assisted, palladium-catalyzed intramolecular direct arylation for the synthesis of novel fused heterocycles
Wu, Jinlong
Nie, Liang
Luo, Jialu
Dai, Wei-Min
SYNLETT, 2007, (17) : 2728 - 2732
[36] ORGN 633-Synthesis of carbo- and heterocycles via palladium-catalyzed intramolecular direct arylation of vinyl iodides
Kadnikov, Dmitry V.
Klisiewicz, Paul
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 236
[37] Synthesis of Tricyclic Isoxazoles via Sequential [3+2] Dipolar Cycloaddition and Palladium-Catalyzed Intramolecular Arylation Reactions
Guo, Dong-Cai
Zhang, Chao
Li, Fei
Zhang, Fenghua
Yu, Fang
He, Yu-Peng
SYNTHESIS-STUTTGART, 2017, 49 (06): : 1356 - 1370
[38] Palladium-Catalyzed Direct Arylation of Imidazolone N-Oxides with Aryl Bromides and Its Application in the Synthesis of GSK2137305
Zhao, He
Wang, Ruifang
Chen, Ping
Gregg, Brian T.
Hsia, Ming Min
Zhang, Wei
ORGANIC LETTERS, 2012, 14 (07) : 1872 - 1875
[39] Synthesis of spiro polycyclic aromatic hydrocarbons by intramolecular palladium-catalyzed arylation
Gonzalez, JJ
Garcia, N
GomezLor, B
Echavarren, AM
JOURNAL OF ORGANIC CHEMISTRY, 1997, 62 (05): : 1286 - 1291
[40] Regioselective Synthesis of the Tetrahydrocarbazole Core of Akuammiline Alkaloids via Palladium-Catalyzed Intramolecular Arylation Reaction
Vampugani, Naga M. R.
Shelke, Ajay B.
Singh, Prashant B.
Ahmad, Asrar
Kapat, Ajoy
JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (07): : 4461 - 4466

← 1 2 3 4 5 →