Entropy production of a Brownian ellipsoid in the overdamped limit

被引:15
|
作者
Marino, Raffaele [1 ,2 ]
Eichhorn, Ralf [1 ,2 ]
Aurell, Erik [3 ,4 ,5 ,6 ,7 ]
机构
[1] Royal Inst Technol, NORDITA, Roslagstullsbacken 23, SE-10691 Stockholm, Sweden
[2] Stockholm Univ, Roslagstullsbacken 23, SE-10691 Stockholm, Sweden
[3] KTH Royal Inst Technol, Dept Computat Biol, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden
[4] KTH Royal Inst Technol, ACCESS Linnaeus Ctr, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden
[5] KTH Royal Inst Technol, Ctr Quantum Mat, AlbaNova Univ Ctr, SE-10691 Stockholm, Sweden
[6] Aalto Univ, Dept Informat & Comp Sci, Espoo, Finland
[7] Aalto Univ, Dept Appl Phys, Espoo, Finland
关键词
INHOMOGENEOUS-MEDIA; KINETIC-THEORY; MOTION; PARTICLES; IRREVERSIBILITY; THERMODYNAMICS; DIFFUSION; LIQUIDS; SYSTEMS;
D O I
10.1103/PhysRevE.93.012132
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We analyze the translational and rotational motion of an ellipsoidal Brownian particle from the viewpoint of stochastic thermodynamics. The particle's Brownian motion is driven by external forces and torques and takes place in an heterogeneous thermal environment where friction coefficients and (local) temperature depend on space and time. Our analysis of the particle's stochastic thermodynamics is based on the entropy production associated with single particle trajectories. It is motivated by the recent discovery that the overdamped limit of vanishing inertia effects (as compared to viscous fricion) produces a so-called "anomalous" contribution to the entropy production, which has no counterpart in the overdamped approximation, when inertia effects are simply discarded. Here we show that rotational Brownian motion in the overdamped limit generates an additional contribution to the "anomalous" entropy. We calculate its specific form by performing a systematic singular perturbation analysis for the generating function of the entropy production. As a side result, we also obtain the (well-known) equations of motion in the overdamped limit. We furthermore investigate the effects of particle shape and give explicit expressions of the "anomalous entropy" for prolate and oblate spheroids and for near-spherical Brownian particles.
引用
收藏
页数:15
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