Towards the total synthesis of colletofragarones: constructing the macrocyclic lactone by high pressure-mediated intramolecular Diels-Alder reaction

被引：15
|
作者：
Marrero, Joaquin G. [1 ]
Harwood, Laurence M. [1 ]
机构：
[1] Univ Reading, Dept Chem, Reading RG6 6AD, Berks, England
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 26期
关键词：
COLLETOTRICHUM-FRAGARIAE; ACID; INHIBITORS;
D O I：
10.1016/j.tetlet.2009.03.063
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We report herein an intramolecular Diels-Alder approach towards the construction of the macrocyclic lactone ring and the perhydrobenzofuran system of the colletofragarones, novel metabolites produced by fungi of the genus Colletotrichum that are responsible for inhibition of germination of the conidia in these species. Crown Copyright (C) 2009 Published by Elsevier Ltd. All rights reserved.
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页码：3574 / 3576
页数：3
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