Synthesis and characterization of hexaaryltellurium (TeAr6); The first neutral hexaarylated element compound

被引:14
|
作者
Minoura, M [1 ]
Sagami, T [1 ]
Miyasato, M [1 ]
Akiba, K [1 ]
机构
[1] HIROSHIMA UNIV,FAC SCI,DEPT CHEM,HIGASHIHIROSHIMA 739,JAPAN
关键词
D O I
10.1016/S0040-4020(97)00552-8
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Te(C6H4-4-CF3)(6) 1a was obtained by the unique one-pot reaction of LiC6H4-4-CF3 with TeCl4. The Te atom resides in the highest oxidation state (Te-VI) having six C-Te bonds in 1a. Compound 1a is extremely thermally stable and not light sensitive unlike tetraorganotellurium compounds. The X-ray crystallographic analysis of 1a revealed a rare example of approximately T-h molecular symmetry. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:12195 / 12202
页数:8
相关论文
共 50 条
  • [32] Synthesis and characterization of a linked, π-π stacked organotin compound of 2-mercapto-6-nitrobenzothiazolyl diphenyltin chloride with 2-ethoxyl-6-nitrobenzothiazole
    Ma, CL
    Jiang, Q
    Zhang, RF
    CANADIAN JOURNAL OF CHEMISTRY, 2003, 81 (07) : 825 - 831
  • [33] Synthesis and characterization of novel one-dimensional chalcogenide compound of K5NaTi6Se27
    Park, Y
    Yun, H
    Oh, H
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 1999, 20 (05) : 605 - 608
  • [34] Synthesis and characterization of the first neutral zinc-sulfur cluster: Zn10S4(SEt)(12)L(4)
    Nyman, MD
    HampdenSmith, MJ
    Duesler, EN
    INORGANIC CHEMISTRY, 1996, 35 (04) : 802 - 803
  • [35] An alkaline tin(II) halide compound Na3Sn2F6Cl: Synthesis, structure, and characterization
    Gong, Pifu
    Luo, Siyang
    Huang, Qian
    Yang, Yi
    Jiang, Xingxing
    Liang, Fei
    Chen, Chuangtian
    Lin, Zheshuai
    JOURNAL OF SOLID STATE CHEMISTRY, 2017, 248 : 104 - 108
  • [36] Synthesis of novel orthophosphate compound AgSr4Cu4.5(PO4)6: Characterization and anticorrosion activities
    Khmiyas, J.
    Kerroum, Y.
    Aoufir, Y. El.
    Guenbour, A.
    Bellaouchou, A.
    Zarrouk, A.
    Assani, A.
    Saadi, M.
    Ammari, L. El.
    CHEMICAL DATA COLLECTIONS, 2022, 41
  • [37] The synthesis and characterization of analogs of the antimicrobial compound squalamine: 6 beta-hydroxy-3-aminosterols synthesized from hyodeoxycholic acid
    Jones, SR
    Kinney, WA
    Zhang, XH
    Jones, LM
    Selinsky, BS
    STEROIDS, 1996, 61 (10) : 565 - 571
  • [38] Synthesis and characterization of heavier group 13 element ferrocenophanes:: The first gallium-bridged [1]ferrocenophane and an unusual indium species
    Schachner, JA
    Lund, CL
    Quail, JW
    Müller, J
    ORGANOMETALLICS, 2005, 24 (18) : 4483 - 4488
  • [39] Synthesis and structural characterization of the first mixed lanthanacarborane incorporating η5-cyclopentadienyl and η6-carboranyl ligands
    Xie, ZW
    Wang, SW
    Zhou, ZY
    Mak, TCW
    ORGANOMETALLICS, 1998, 17 (10) : 1907 - 1909
  • [40] Synthesis, characterization and catalytic behaviors of neutral nickel complexes:: Arylnickel N-alkyl-6-(1-(arylimino)ethyl)picolinamide
    Shen, Miao
    Hao, Peng
    Sun, Wen-Hua
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (8-9) : 1683 - 1695