Metal oxidation promoted C-H activation in manganese complexes of N-confused porphyrin

被引：72
|
作者：
Bohle, DS
Chen, WC
Hung, CH [1 ]
机构：
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
[2] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA
来源：
INORGANIC CHEMISTRY | 2002年 / 41卷 / 13期
关键词：
D O I：
10.1021/ic025573m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The N-confused porphyrin complex Mn-II(NCHPP)Br exhibits a nonplanar porphyrin ring with an inner core C-H on the inverted pyrrole ring. The aerobic metal oxidation promotes the dissociation of an inner-core proton on the inverted pyrrole ring and changes the N-confused porphyrin conformation to a planar porphyrin ring to form Mn-III(NCPP)Br. The conjugate systems and metal oxidation states are confirmed by crystal structures as well as spectroscopic data. The reverse reaction can be achieved by treating the Mn-III(NCPP)Br with p-toluenesulfonhydrazide.
引用
收藏
页码：3334 / 3336
页数：3
相关论文
共 50 条
  • [31] Alkene C-H activations at dinuclear complexes promoted by oxidation
    Jiménez, MV
    Sola, E
    Caballero, J
    Lahoz, FJ
    Oro, LA
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (07) : 1208 - +
  • [32] Ni(III) complex of an N-confused porphyrin inner C-oxide
    Xiao, ZW
    Patrick, BO
    Dolphin, D
    INORGANIC CHEMISTRY, 2003, 42 (25) : 8125 - 8127
  • [33] Intramolecular C-H•••π interactions in metal-porphyrin complexes
    Bogdanovic, GA
    Medakovkic, V
    Milcic, MK
    Zaric, SD
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2004, 5 (4-7) : 174 - 185
  • [34] Structures and ligand exchange of N-confused porphyrin dimer complexes with group 12 metals
    Furuta, H
    Morimoto, T
    Osuka, A
    INORGANIC CHEMISTRY, 2004, 43 (05) : 1618 - 1624
  • [35] N-Confused Porphyrin Immobilized on Solid Supports: Synthesis and Metal Ions Sensing Efficacy
    Gamelas, Sara R. D.
    Gomes, Ana T. P. C.
    Nuno, M. M. Moura
    Faustino, Maria A. F.
    Cavaleiro, Jose A. S.
    Lodeiro, Carlos
    Verissimo, Marta I. S.
    Fernandes, Tiago
    Daniel-da-Silva, Ana L.
    Gomes, M. Teresa S. R.
    Neves, Maria G. P. M. S.
    MOLECULES, 2018, 23 (04):
  • [36] Highly porous, N-confused porphyrin-based metal-organic frameworks
    Yang, Yufeng
    Sakashita, Ryuichi
    Ishida, Masatoshi
    Furuta, Hiroyuki
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [37] Importance of the C-H•••N weak hydrogen bonding on the coordination structures of manganese(III) porphyrin complexes
    Ikezaki, A
    Nakamura, M
    INORGANIC CHEMISTRY, 2003, 42 (07) : 2301 - 2310
  • [38] Doubly N-confused porphyrin: A new complexing agent capable of stabilizing higher oxidation states
    Furuta, H
    Maeda, H
    Osuka, A
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (05) : 803 - 807
  • [39] Doubly N-confused porphyrin: A new complexing agent capable of stabilizing higher oxidation states
    Furuta, Hiroyuki
    Maeda, Hiromitsu
    Osuka, Atsuhiro
    1600, American Chemical Society (122):
  • [40] C-H ACTIVATION BY ELECTROPHILIC METAL-COMPLEXES
    SEN, A
    KAO, LC
    GRETZ, E
    OLIVER, TF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 199 : 35 - CATL
12345