Metal oxidation promoted C-H activation in manganese complexes of N-confused porphyrin

被引：72
|
作者：
Bohle, DS
Chen, WC
Hung, CH [1 ]
机构：
[1] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
[2] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA
来源：
INORGANIC CHEMISTRY | 2002年 / 41卷 / 13期
关键词：
D O I：
10.1021/ic025573m
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The N-confused porphyrin complex Mn-II(NCHPP)Br exhibits a nonplanar porphyrin ring with an inner core C-H on the inverted pyrrole ring. The aerobic metal oxidation promotes the dissociation of an inner-core proton on the inverted pyrrole ring and changes the N-confused porphyrin conformation to a planar porphyrin ring to form Mn-III(NCPP)Br. The conjugate systems and metal oxidation states are confirmed by crystal structures as well as spectroscopic data. The reverse reaction can be achieved by treating the Mn-III(NCPP)Br with p-toluenesulfonhydrazide.
引用
收藏
页码：3334 / 3336
页数：3
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