RETRACTED: Neomycin and gentamicin detection via molecular recognition with cyclam-decorated gold nanoparticles (Retracted article. See FEB, 2023)

被引:12
|
作者
Yeluri, Tanuja [1 ]
Bhosale, Rajesh S. [1 ]
Ghule, Namdev V. [1 ]
Raynor, Aaron M. [2 ]
Bhosale, Sidhanath V. [1 ]
Bhosale, Sheshanath V. [2 ]
机构
[1] CSIR, Indian Inst Chem Technol, Polymers & Funct Mat Div, Hyderabad 500007, Telangana, India
[2] RMIT Univ, Sch Appl Sci, Melbourne, Vic 3001, Australia
基金
澳大利亚研究理事会;
关键词
gold nanoparticles; colorimetric detection; aminoglycoside; naked-eye detection; hydrogen-bonding; COLORIMETRIC DETERMINATION; ASSAY; PHARMACOKINETICS; ANTIBIOTICS; MELAMINE;
D O I
10.1080/10610278.2015.1071819
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Herein we describe the development of cyclam-coated gold nanoparticles (cyclam-Au NPs) based sensitive colorimetric method for neomycin and gentamicin detection. The cyclam-Au NPs were characterised by UV-vis spectroscopy, fourier transform infrared spectroscopy, transmission electron microscopy techniques, dynamic light scattering and zeta potential measurements. The cyclam-Au NPs aggregated in presence of neomycin and gentamicin, which results a colour change from violet to blue. The characteristic absorption peak at 530nm was bathochromic-shifted to a longer wavelength (660nm). This confirms the aggregation of cyclam-Au NPs in the presence of neomycin as well as gentamicin via hydrogen bonding. The UV-vis absorption measurements employed to determine detection limit of neomycin and gentamicin. The detection limit is 1.87x10(-8)M and 2.35x10(-8)M for neomycin and gentamicin respectively.
引用
收藏
页码:772 / 779
页数:8
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