Allylation of prochiral C-nucleophiles catalyzed by the Pd(0)-(S)-(-)-BINAP complex

被引:0
|
作者
Lozanova, A. V. [1 ]
Ugurchieva, T. M. [1 ]
Veselovsky, V. V. [1 ]
机构
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
关键词
allylation; C-nucleophiles; palladium complexes; phosphines;
D O I
10.1007/s11172-008-0239-9
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The allylation of prochiral C-nucleophiles catalyzed by the Pd(0)-(S)-(-)-BINAP complex (BINAP is 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl) was studied. The enantioselectivity of the allylation was found to be low.
引用
收藏
页码:1787 / 1789
页数:3
相关论文
共 50 条
  • [21] Pd-porphyrin complex-catalyzed allylation of indole with allylic alcohols through C3-C2 coupling
    Atia, Alaa A.
    Kimura, Masanari
    TETRAHEDRON, 2021, 90
  • [22] FeCl3 catalyzed 1,6-conjugate addition of phenol C-nucleophiles: Facile synthesis of diarylmethanes
    Sreenivas, Kukkamudi
    Khan, Faiz Ahmed
    TETRAHEDRON, 2020, 76 (06)
  • [23] Pd-catalyzed C4-Dearomative Allylation of Benzyl Ammoniums with Allyltributylstannane
    Kayashima, Yuki
    Komatsuda, Masaaki
    Muto, Kei
    Yamaguchi, Junichiro
    CHEMISTRY LETTERS, 2020, 49 (07) : 836 - 839
  • [24] Activation of Kenner's N-acyl sulfonamide "safety-catch" linker using Pd(0)-catalyzed allylation.
    He, Y
    Kiessling, LL
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 226 : U111 - U112
  • [25] Evidence of formation of an exo-π-allyl complex intermediate in the Pd0-catalyzed alkylation of a bicyclic allylic diacetate with stabilized carbon nucleophiles
    Brunel, JM
    Maffei, M
    Muchow, G
    Buono, G
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2000, 2000 (09) : 1799 - 1803
  • [26] Experimental evidence on the existence of an exo-π-allyl complex intermediate in the Pd0-catalyzed alkylation of a bicyclic allylic diacetate with stabilized nucleophiles
    Brunel, JM
    Maffei, M
    Muchow, G
    Buono, G
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2001, 2001 (05) : 1009 - 1012
  • [27] N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles
    Zhang, Wei
    Wang, Fei
    Hu, Jinbo
    ORGANIC LETTERS, 2009, 11 (10) : 2109 - 2112
  • [28] SYNTHESIS, PROPERTIES, AND REACTIONS WITH C-NUCLEOPHILES OF (PHENYLOXAZOLINE)TRICARBONYLCHROMIUM(O), (PHENYLMETHANIMINE)TRICARBONYLCHROMIUM(O), AND (BENZALDEHYDE HYDRAZONE)TRICARBONYLCHROMIUM(0) COMPLEXES
    KUNDIG, EP
    RIPA, A
    LIU, RG
    AMURRIO, D
    BERNARDINELLI, G
    ORGANOMETALLICS, 1993, 12 (09) : 3724 - 3737
  • [29] Et3B-promoted, Pd(0)-catalyzed allylation of active methylene compounds with allylic alcohols
    Tamaru, Y
    Horino, Y
    Araki, M
    Tanaka, S
    Kimura, M
    TETRAHEDRON LETTERS, 2000, 41 (30) : 5705 - 5709
  • [30] Carbonyl allylation of aldehydes catalyzed by a silica-supported poly-γ-diphenylarsinopropylsiloxane palladium(0) complex
    Cai, MZ
    Huang, YH
    Zhao, H
    Zhang, RL
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2004, 689 (15) : 2436 - 2440