Electrochemical reduction of nickel complexes with 2,2′-bipyridine

被引：25
|
作者：
Budnikova, YG [1 ]
Yakhvarov, DG
Morozov, VI
Kargin, YM
Il'yasov, AV
Vyakhireva, YN
Sinyashin, OG
机构：
[1] Russian Acad Sci, Kazan Sci Ctr, Arbuzov Inst Organ & Phys Chem, Kazan, Tatarstan, Russia
[2] Kazan VI Lenin State Univ, Kazan 420008, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 02期
关键词：
Nickel; Active Form; Bipyridine; Electrochemical Reduction; Ligand Concentration;
D O I：
10.1023/A:1015401029839
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electrochemical reduction of a nickel complex with 2,2'-bipyridine is accompanied by competing coproportionation yielding paramagnetic Ni-I complexes. A decrease in the ligand concentration shifts the equilibrium to the side of the active form of the Ni(o)bipy catalyst.
引用
收藏
页码：168 / 172
页数：5
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