[2,6-(Trip)2H3C6](Cp*)Si: A Stable Monomeric Arylsilicon(II) Compound

被引：50

作者：

Jutzi, Peter ^{[1
]}

Leszczynska, Kinga ^{[1
]}

Neumann, Beate ^{[1
]}

Schoeller, Wolfgang W. ^{[1
]}

Stammler, Hans-Georg ^{[1
]}

机构：

[1] Univ Bielefeld, Fac Chem, D-33615 Bielefeld, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 14期

关键词：

pi interactions; carbene homologues; silicon; silylenes; subvalent compounds; SILICON DOUBLE-BOND; MAIN-GROUP ELEMENTS; DIVALENT SILICON; SILYLENES; CHEMISTRY; DECAMETHYLSILICOCENE; DISILENES; COMPLEXES; CATION;

D O I：

10.1002/anie.200805749

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Si takes a rest: A bulky σ-bound terphenyl substituent and a π-bound Cp* ligand enable the isolation and full characterization of the first aryl-substituted, monomeric silicon(II) compound 1, which can be regarded as the "resting state" of a true silylene containing a σ-bound Cp* group. The conformation of the aryl group prevents aryl-Si π back-bonding. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2596 / 2599

页数：4

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