Porous anatase TiO2 constructed from a metal-organic framework for advanced lithium-ion battery anodes

被引：155

作者：

Wang, Ziqi ^{[1
]}

Li, Xiang ^{[1
]}

Xu, Hui ^{[1
]}

Yang, Yu ^{[1
]}

Cui, Yuanjing ^{[1
]}

Pan, Hongge ^{[1
]}

Wang, Zhiyu ^{[1
]}

Chen, Banglin ^{[1
,2
]}

Qian, Guodong ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Mat Sci & Engn, Cyrus Tang Ctr Sensor Mat & Applicat, State Key Lab Silicon Mat, Hangzhou 310027, Peoples R China

[2] Univ Texas San Antonio, Dept Chem, San Antonio, TX 78249 USA

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 31期

基金：

中国国家自然科学基金;

关键词：

CARBON; PERFORMANCE; NANOPARTICLES; SULFUR; PORES; MICROSPHERES; ARCHITECTURE; RECOGNITION; PLATFORMS; TEMPLATE;

D O I：

10.1039/c4ta02029d

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Porous anatase TiO2 has been prepared, for the first time, through the calcination of a metal-organic framework (MOF) precursor under an air atmosphere at 380 degrees C. The resulting TiO2 has shown moderate porosity with a BET surface area of 220 m(2) g(-1) attributed to the highly porous structure of the MIL-125(Ti) precursor. The porous anatase TiO2 was examined as a lithium-ion battery anode, exhibiting high capacity retention and good rate capability. The porous structure of anatase TiO2 enforces Li+ diffusion and helps to buffer the volumetric variation. It has shown reversible capacities of 166, 106 and 71 mA h g(-1) at 1 C, 5 C and 10 C charge/discharge rates, respectively, after 500 cycles.

引用

页码：12571 / 12575

页数：5

共 50 条

[41] Preparation and physico-chemical investigation of anatase TiO2 nanotubes for a stable anode of lithium-ion battery
Fasakin, O.
Oyedotun, Kabir O.
Kebede, Mesfin
Rohwer, Mark
Le Roux, Lukas
Mathe, Mkhulu
Eleruja, M. A.
Ajayi, E. O. B.
Manyala, Ncholu
ENERGY REPORTS, 2020, 6 : 92 - 101
[42] Carbon nanospheres derived from sunflower seed husk composited with anatase TiO2 used as anode for lithium-ion battery
Li, Xiangji
Wang, Xinyan
Xu, Xi
Yu, Kaifeng
Liang, Ce
IONICS, 2022, 28 (04) : 1635 - 1646
[43] Effect of anatase phase on electrochemical properties of the TiO2(B) negative electrode for lithium-ion battery application
Kim, Bo-Ra
Yun, Kang-Seop
Jung, Hee-June
Myung, Seung-Taek
Jung, Sang-Chul
Kang, Wooseung
Kim, Sun-Jae
CURRENT APPLIED PHYSICS, 2013, 13 : S148 - S151
[44] The electrochemical performances of high surface area mesocellular anatase TiO2 foam anode for lithium-ion battery
Han, Do Kyeong
Park, Minsun
Huh, Seong
Won, Yong Sun
MATERIALS CHEMISTRY AND PHYSICS, 2024, 315
[45] Carbon nanospheres derived from sunflower seed husk composited with anatase TiO2 used as anode for lithium-ion battery
Xiangji Li
Xinyan Wang
Xi Xu
Kaifeng Yu
Ce Liang
Ionics, 2022, 28 : 1635 - 1646
[46] Facile formation of a nanostructured NiP2@C material for advanced lithium-ion battery anode using adsorption property of metal-organic framework
Li, Gaihua
Yang, Hao
Li, Fengcai
Du, Jia
Shi, Wei
Cheng, Peng
JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (24) : 9593 - 9599
[47] Redox Targeting of Anatase TiO2 for Redox Flow Lithium-Ion Batteries
Pan, Feng
Yang, Jing
Huang, Qizhao
Wang, Xingzhu
Huang, Hui
Wang, Qing
ADVANCED ENERGY MATERIALS, 2014, 4 (15)
[48] Particle Size Effect of Anatase TiO2 Nanocrystals for Lithium-Ion Batteries
Kang, J. W.
Kim, D. H.
Mathew, V.
Lim, J. S.
Gim, J. H.
Kimz, J.
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2011, 158 (02) : A59 - A62
[49] Pseudocapacitive Lithium-Ion Storage in Oriented Anatase TiO2 Nanotube Arrays
Zhu, Kai
Wang, Qing
Kim, Jae-Hun
Pesaran, Ahmad A.
Frank, Arthur J.
JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (22): : 11895 - 11899
[50] Metal-Organic Frameworks and Their Derivatives as Cathodes for Lithium-Ion Battery Applications: A Review
Reddy, R. Chenna Krishna
Lin, Xiaoming
Zeb, Akif
Su, Cheng-Yong
ELECTROCHEMICAL ENERGY REVIEWS, 2022, 5 (02) : 312 - 347

← 1 2 3 4 5 →