Bis(ethanol-κO)bis(pyridine-3-carbaldehyde-κN thiosemicarbazone)bis(thiocyanato-κN)iron(II)-pyridine-3-carbaldehyde thiosemicarbazone (1/2)

被引：1
|
作者：
Wang, Shao-Mei [1 ]
机构：
[1] Anyang Normal Univ, Coll Chem & Chem Engn, Anyang 455000, Henan, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词：
D O I：
10.1107/S1600536809024076
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title Fe-II complex, [Fe(NCS)(2)(C7H8N4S)(2)(CH3CH2OH)(2)]center dot 2C(7)H(8)N(4)S, based on the Schiff base ligand pyridine-3-carbaldehyde thiosemicarbazone (pct), results from the cocrystallization of an Fe-II coordination compound together with two of the pct ligands. The complex unit is mononuclear, with the central Fe-II ion located on a crystallographic centre of inversion and coordinated by four N atoms from two pct ligands and two thiocyanate anions. The slightly distorted octahedral coordination is completed by two O atoms from ethanol molecules. The crystal packing is accomplished intermolecular N-H center dot center dot center dot S hydrogen bonds.
引用
收藏
页码：M847 / U246
页数：11
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