Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects

被引：19

作者：

Griffiths, Kieran ^{[1
]}

Dokorou, Vassiliki N. ^{[1
]}

Spencer, John ^{[1
]}

Abdul-Sada, Alaa ^{[1
]}

Vargas, Alfredo ^{[1
]}

Kostakis, George E. ^{[1
]}

机构：

[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 05期

基金：

英国工程与自然科学研究理事会;

关键词：

SINGLE-MOLECULE MAGNET; GAUSSIAN-BASIS SETS; CRYSTAL-STRUCTURES; DY-III; STRUCTURE VALIDATION; CARBONYL CLUSTERS; ORBITAL METHODS; WAVE-FUNCTIONS; GD-III; COMPLEXES;

D O I：

10.1039/c5ce02109j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR(2)Ln(2)(LX)(4)(NO3)(2)]solv)(2)] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)(3) salts. Our synthetic work is further supported by DFT studies.

引用

页码：704 / 713

页数：10

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