Isoskeletal Schiff base polynuclear coordination clusters: synthetic and theoretical aspects

被引：19
|
作者：
Griffiths, Kieran [1 ]
Dokorou, Vassiliki N. [1 ]
Spencer, John [1 ]
Abdul-Sada, Alaa [1 ]
Vargas, Alfredo [1 ]
Kostakis, George E. [1 ]
机构：
[1] Univ Sussex, Sch Life Sci, Dept Chem, Brighton BN1 9QJ, E Sussex, England
来源：
CRYSTENGCOMM | 2016年 / 18卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
SINGLE-MOLECULE MAGNET; GAUSSIAN-BASIS SETS; CRYSTAL-STRUCTURES; DY-III; STRUCTURE VALIDATION; CARBONYL CLUSTERS; ORBITAL METHODS; WAVE-FUNCTIONS; GD-III; COMPLEXES;
D O I：
10.1039/c5ce02109j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This work addresses and enlightens synthetic aspects derived from our effort to systematically construct isoskeletal tetranuclear coordination clusters (CCs) of the general formula [TR(2)Ln(2)(LX)(4)(NO3)(2)]solv)(2)] possessing a specific defected dicubane topology, utilizing various substituted Schiff base organic ligands (H2LX) and NiII/CoII and Dy(OTf)(3) salts. Our synthetic work is further supported by DFT studies.
引用
收藏
页码：704 / 713
页数：10
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