In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins

被引：92
|
作者：
RajanBabu, T. V. [1 ]
机构：
[1] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
来源：
SYNLETT | 2009年 / 06期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
carbon-carbon bond formation; hydrovinylations; asymmetric catalysis; ligand effects; transition metals; NICKEL-CATALYZED HYDROVINYLATION; CHAIN STEREOCHEMISTRY PROBLEM; STEROID SIDE-CHAINS; WHIP PSEUDOPTEROGORGIA-ELISABETHAE; C-C LINKAGES; ASYMMETRIC HYDROVINYLATION; PHOSPHORAMIDITE LIGANDS; HIGHLY EFFICIENT; ENANTIOSELECTIVE HYDROVINYLATION; STYRENE DERIVATIVES;
D O I：
10.1055/s-0028-1088213
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Attempts to introduce the highly versatile vinyl group into other organic molecules in a chemo-, regio-, and stereoselective fashion via catalytic activation of ethylene provided challenging opportunities to explore new ligand and salt effects in homogeneous catalysis. This review provides a personal account of the development of enantioselective reactions involving ethylene.
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页码：853 / 885
页数：33
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