The role of N-heterocyclic carbene substituents on ruthenium(II) complexes in the catalytic transfer hydrogenation of acetophenone

被引：5

作者：

Gunay, Muhammet Emin ^{[1
]}

Gencay Cogaslioglu, Gulcan ^{[1
]}

机构：

[1] Adnan Menderes Univ, Fac Arts & Sci, Dept Chem, Aydin, Turkey

来源：

TURKISH JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 02期

关键词：

N-heterocyclic carbene ligands; substituent effect; transfer hydrogenation; ruthenium complexes; silver-N-heterocyclic carbene complexes; ASYMMETRIC TRANSFER HYDROGENATION; RHODIUM(I) COMPLEXES; LIGANDS; REACTIVITY; ALDEHYDES; EFFICIENT; KETONES;

D O I：

10.3906/kim-1506-15

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel ruthenium(II) complexes [RuCl2 (NHC)(p-cymene)], 3a e, containing 1-alkyl-3-benzylimidazol2-ylidene ligands were prepared. All synthesized compounds were characterized by NMR spectroscopy and elemental analyses. Ru(II)-NHC complexes were tested as catalysts for the transfer hydrogenation of acetophenone, showing modest to high activity in this reaction. The results revealed that efficiencies depend on the substituents of the benzene ring of the benzyl on the N atom of the NHC ring.

引用

页码：296 / 304

页数：9

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