Diorganotin(IV) derivatives of arenephosphinothiol ligands.: The crystal structure of [Ph2Sn{2-Ph2P)C6H4S}2] and [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H3S}2]

被引：10

作者：

Pérez-Lourido, P

Romero, J ^{[1
]}

García-Vazquez, JA

Sousa, A

Zubieta, J

Russo, U

机构：

[1] Univ Santiago de Compostela, Fac Quim, Dept Quim Inorgan, E-15706 Santiago, Galicia, Spain

[2] Univ Vigo, Dept Quim Inorgan, Pontevedra, Spain

[3] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

[4] Univ Padua, Dipartimento Chim Inorgan Met Organ & Analit, Padua, Italy

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2000年 / 595卷 / 01期

关键词：

organotin complexes; tin complexes; phosphinothiolate complexes; crystal structure;

D O I：

10.1016/S0022-328X(99)00568-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The diorganotin complexes, [Me2Sn{2-(Ph2P)C6H4S}(2)] (1), [Ph2Sn{2-(Ph2P)C6H4S}(2)] (2), [Me2Sn{2-(Ph2PO)-6-(Me3Si)C6H3S}(2)] (3) and [Ph2Sn{2-(Ph2PO)-6-(Me3Si)C6H4S}(2)] (4), have been prepared by reacting the corresponding diorganotin(IV) chloride with 2-(Ph2P)C6H4SH and 2-(Ph2PO)-6-(Me3Si)C6H3SH. Compound 2 crystallises in the monoclinic space group and the tin atom is tetrahedrally coordinated to two ligands acting as monodentate through the thiolate sulphur atoms. Compound 3 also crystallises in the monoclinic space group and, in this compound, the tin atom is octahedrically coordinated [SnC2O2S2]. Spectral data for the complexes (IR, NMR, FAB and Mossbauer spectra) are discussed and related to the structural information. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：59 / 65

页数：7

共 50 条

[21] Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium cluster ”Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}”
A. A. Koridze
S. A. Kuklin
N. A. Shtelzer
P. V. Petrovskii
F. M. Dolgushin
M. G. Ezernitskaya
Russian Chemical Bulletin, 2008, 57 : 2194 - 2197
[22] Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium cluster "Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}"
Koridze, A. A.
Kuklin, S. A.
Shtelzer, N. A.
Petrovskii, P. V.
Dolgushin, F. M.
Ezernitskaya, M. G.
RUSSIAN CHEMICAL BULLETIN, 2008, 57 (10) : 2194 - 2197
[23] SULFUR SUBSTITUTED ORGANOTIN COMPOUNDS .10. PREPARATIONS AND REACTIONS OF PH3SN(CH2)NSOC6H4ME-P(N = 3 OR 4) AND PH3SN(CH2)NSO2C6H4ME-P(N = 2, 3 OR 4)
WARDELL, JL
WIGZELL, JM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 244 (03) : 225 - 233
[24] Synthesis and characterization of rhenium phosphinothiolate complexes.: Crystal and molecular structures of [HNEt3][Re{P(C6H4S)3}2], [ReOCl{OP(C6H5)2(C6H4S)}{P(C6H5)2(C6H4S)}], [Re2O5{P(C6H5)2(C6H4S)}2], and [ReOCl{OP(C6H5)2(2-SC6H3-3-SiMe)}2]
Perez-Lourido, P
Romero, J
Garcia-Vazquez, J
Sousa, A
Maresca, KP
Rose, DJ
Zubieta, J
INORGANIC CHEMISTRY, 1998, 37 (13) : 3331 - 3336
[25] SYNTHESIS AND SPECTROSCOPIC AND X-RAY STRUCTURAL STUDIES OF THE MESITYLPHOSPHINES PH22,4,6-ME3C6H2 AND PH2,4,6-ME3C6H2 AND THEIR LITHIUM-SALTS [LI(THF)3PH2,4,6-ME3C6H2] AND [(LI(OET2)P2,4,6-ME3C6H22)2]
BARTLETT, RA
OLMSTEAD, MM
POWER, PP
SIGEL, GA
INORGANIC CHEMISTRY, 1987, 26 (12) : 1941 - 1946
[26] Ni(II) complexes with thioether-functionalized silylamide ligands. Synthesis and crystal structures of [Ni{Me2Si(N-C6H4-2-S-t-Bu)2}], [Ni{Ph2Si(N-C 6H4-2-SMe)2}] and [Ni{Ph2Si(N-C6H4-2-SPh)2}]
Albrecht, Ralf
Liebing, Phil
Morgenstern, Uwe
Wagner, Christoph
Merzweiler, Kurt
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2019, 74 (02): : 233 - 240
[27] SYNTHESES AND CRYSTAL-STRUCTURES OF 2 BULKY AMINOHALOGENOSTANNANES, [(ME3SI)2CH]2SN(CL)N(H)(C6H2-2,4,6-TERT-BU3) AND [(ME3SI)2CH]2SN(F)N(H)(C6H2-2,4,6-TERT-BU3)
RAHARINIRINA, A
BOESE, R
SCHMID, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (01) : 39 - 45
[28] [{2,6-(Me2NCH2)2C6H3}Sn]2:: An intramolecularly coordinated diorganodistannyne
Jambor, Roman
Kasna, Blanka
Kirschner, Karl N.
Schuermann, Markus
Jurkschat, Klaus
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (09) : 1650 - 1653
[29] Hypervalent tellurium compounds containing N→Te intramolecular interactions.: Crystal and molecular structure of [2-(Me2NCH2)C6H4]2Te2, [2-(Me2NCH2)C6H4]TeS(S)PR2 (R = Me, Ph, OPri) and [2-(Me2NCH2)C6H4]Te-S-PPh2=N-PPh2=S
Drake, JE
Hursthouse, MB
Kulcsar, M
Light, ME
Silvestru, A
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 623 (1-2) : 153 - 160
[30] Organotin(IV) complexes of 4,6-dimethylpyrimidine-2-thione, Me2PymtH.: Preparation, characterization and crystal structure determination of cis-[Ph2Sn(Me2Pymt)2] and [Ph3Sn(Me2Pymt)]
Fernandes, RM
Lang, ES
López, EMV
de Sousa, GF
POLYHEDRON, 2002, 21 (12-13) : 1149 - 1153

← 1 2 3 4 5 →