Molecular magnets based on charge transfer complexes

被引:13
|
作者
Enoki, T [1 ]
Enomoto, M [1 ]
Enomoto, M [1 ]
Yamaguchi, K [1 ]
Yoneyama, N [1 ]
Yamaura, J [1 ]
Miyazaki, A [1 ]
Saito, G [1 ]
机构
[1] KYOTO UNIV,DEPT CHEM,SAKYO KU,KYOTO 606,JAPAN
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1996年 / 285卷
关键词
D O I
10.1080/10587259608030773
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We investigated two classes of organic charge transfer complexes in the TTF family and related materials, in order to aim at the development of novel magnetic systems. The first one is the complexes with transition metal d-electrons having localized magnetic moments, where the pi-electrons in organic donors play an important role in the exchange interaction mechanism between the Localized magnetic moments of d-electrons. The second class is obtained on the basis of the localized magnetic moments of pi-electrons, where the on-site Coulomb interaction in organic donors overwhelms the transfer integral.
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页码:19 / 26
页数:8
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