Triethylammonium Halochromates, (C2H5)3NH+[CrO3X]- (X=F ,Cl), Reagents for Efficient Oxidation Coupling of Thiols to Disulfides

被引：0

作者：

Mohammadi, Mohammad Kazem ^{[1
,3
]}

Ghammamy, Shahriare ^{[2
]}

Farjam, Mohammad Hossein

机构：

[1] Islamic Azad Univ, Fac Sci, Ahwaz Branch, Tehran, Iran

[2] Imam Khomeini Int Univ, Fac Sci, Dept Chem, Qazvin 288, Iran

[3] Islamic Azad Univ, Fac Sci, Firoozabad Branch, Tehran, Iran

来源：

CHEMISTRY AND CHEMICAL PROCESS | 2011年

关键词：

Thiol; Oxidation; Disulfide; Triethylammonium Fluorochromate; Triethylammonium Chlorochromate; Solution; Microwave; CONVERSION; BROMINE; SYSTEM;

D O I：

暂无

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Triethylammonium fluorochromate (TriEAFC) and Triethylammonium chlorochromate (TriEACC) are new efficient reagents, which are prepared easily and oxidized thiols to the corresponding disulfides swiftly. The reactions perform cleanly and terminate simultaneously at the disulfide stage without any side products. Oxidizing of some thiols to their corresponding disulfides was studied in solution at room temperature and under microwave radiation. The easy procedure, simple work-up, short reaction times, and excellent yields are advantages of these reagents.

引用

页码：215 / 219

页数：5

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