Interaction energy and force for a pair of colloidal particles in a bidisperse hard-sphere solvent

被引:13
|
作者
Henderson, D [1 ]
Trokhymchuk, AD
Wasan, DT
机构
[1] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[2] Natl Acad Sci Ukraine, Inst Condensed Matter Phys, UA-79011 Lvov, Ukraine
[3] IIT, Dept Environm Chem & Engn, Chicago, IL 60612 USA
关键词
colloidal suspensions; potential of mean force; interaction energy;
D O I
10.1016/S0167-7322(03)00271-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A convenient approximation is proposed for the correlation function of a pair of large hard-sphere particles in a bidisperse or binary hard-sphere mixture. This approximation is based on the solution of the Ornstein-Zernike/Percus-Yevick integral equations for a hard-sphere mixture. From this result, we obtain the potential of mean force and interaction force for a pair of colloidal spheres in a bidisperse hard-sphere fluid. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:21 / 28
页数:8
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