Sulfiphilic Nickel Phosphosulfide Enabled Li2S Impregnation in 3D Graphene Cages for Li-S Batteries

被引：150
|
作者：
Zhou, Guangmin [1 ]
Sun, Jie [1 ]
Jin, Yang [1 ]
Chen, Wei [1 ]
Zu, Chenxi [1 ]
Zhang, Rufan [1 ]
Qiu, Yongcai [1 ]
Zhao, Jie [1 ]
Zhuo, Denys [1 ]
Liu, Yayuan [1 ]
Tao, Xinyong [1 ]
Liu, Wei [1 ]
Yan, Kai [1 ]
Lee, Hye Ryoung [1 ]
Cui, Yi [1 ,2 ]
机构：
[1] Stanford Univ, Dept Mat Sci & Engn, Stanford, CA 94305 USA
[2] SLAC Natl Accelerator Lab, Stanford Inst Mat & Energy Sci, 2575 Sand Hill Rd, Menlo Pk, CA 94025 USA
来源：
ADVANCED MATERIALS | 2017年 / 29卷 / 12期
关键词：
LITHIUM-SULFUR BATTERY; CATHODE; COMPOSITES; PARTICLES; ELECTRODE; PROGRESS; SPHERES;
D O I：
10.1002/adma.201603366
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A 3D graphene cage with a thin layer of electrodeposited nickel phosphosulfide for Li2S impregnation, using ternary nickel phosphosulphide as a highly conductive coating layer for stabilized polysulfide chemistry, is accomplished by the combination of theoretical and experimental studies. The 3D interconnected graphene cage structure leads to high capacity, good rate capability and excellent cycling stability in a Li2S cathode.
引用
收藏
页数：11
相关论文
共 50 条
  • [21] Lowering the charge overpotential of Li2S via the inductive effect of phenyl diselenide in Li-S batteries
    Fan, Qianqian
    Li, Baohua
    Si, Yubing
    Fu, Yongzhu
    CHEMICAL COMMUNICATIONS, 2019, 55 (53) : 7655 - 7658
  • [22] Y2S3-Doped Li2S Active Cathode Materials for All-Solid-State Li-S Batteries
    Hikima, Kazuhiro
    Fujii, Ryo
    Gamo, Hirotada
    Tsukasaki, Hirofumi
    Mori, Shigeo
    Watanabe, Toshiki
    Yamamoto, Kentaro
    Uchimoto, Yoshiharu
    Muto, Hiroyuki
    Matsuda, Atsunori
    JOURNAL OF PHYSICAL CHEMISTRY C, 2023, 127 (28): : 13511 - 13517
  • [23] A 3D MoS2/Graphene Microsphere Coated Separator for Excellent Performance Li-S Batteries
    Yang, Shuang
    Zhang, Junfan
    Tan, Taizhe
    Zhao, Yan
    Liu, Ning
    Li, Haipeng
    MATERIALS, 2018, 11 (10)
  • [24] 3D Printed Li-S Batteries with In Situ Decorated Li2S/C Cathode: Interface Engineering Induced Loading-Insensitivity for Scaled Areal Performance
    Xue, Lanxin
    Zeng, Li
    Kang, Wenbin
    Chen, Haiyan
    Hu, Yin
    Li, Yaoyao
    Chen, Wei
    Lei, Tianyu
    Yan, Yichao
    Yang, Chengtao
    Hu, Anjun
    Wang, Xianfu
    Xiong, Jie
    Zhang, Chuhong
    ADVANCED ENERGY MATERIALS, 2021, 11 (14)
  • [25] Manipulating Electrocatalytic Li2S Redox via Selective Dual-Defect Engineering for Li-S Batteries
    Shi, Zixiong
    Sun, Zhongti
    Cai, Jingsheng
    Yang, Xianzhong
    Wei, Chaohui
    Wang, Menglei
    Ding, Yifan
    Sun, Jingyu
    ADVANCED MATERIALS, 2021, 33 (43)
  • [26] Uniform growth of Li2S promoted by an organophosphorus-based mediator for high rate Li-S batteries
    Yang, Ting
    Liu, Kunlin
    Ren, Ruize
    Zhang, Jizong
    Zheng, Xuewen
    Wang, Chengyang
    Chen, Mingming
    CHEMICAL ENGINEERING JOURNAL, 2020, 381
  • [27] Robust Electrocatalytic Li2S Redox of Li-S Batteries Facilitated by Rationally Fabricated Dual-Defects
    Cui, Yingyue
    Li, Jin
    Cai, Yingjun
    Zhang, Haitao
    Zhang, Suojiang
    SMALL, 2022, 18 (44)
  • [28] Design Multifunctional Catalytic Interface: Toward Regulation of Polysulfide and Li2S Redox Conversion in Li-S Batteries
    Fan, Shuang
    Huang, Shaozhuan
    Pam, Mei Er
    Chen, Song
    Wu, Qingyun
    Hu, Junping
    Wang, Ye
    Ang, Lay Kee
    Yan, Congcong
    Shi, Yumeng
    Yang, Hui Ying
    SMALL, 2019, 15 (51)
  • [29] Mathematical modeling of the charging process of Li-S batteries by incorporating the size-dependent Li2S dissolution
    Xiong, C.
    Zhao, T. S.
    Ren, Y. X.
    Jiang, H. R.
    Zhou, X. L.
    ELECTROCHIMICA ACTA, 2019, 296 : 954 - 963
  • [30] DNA-Guided Li2S Nanostructure Deposition for High-Sulfur-Loaded Li-S Batteries
    Li, Man
    Song, Seunghyun
    Li, Yang
    Chen, Tao
    Bae, Joonho
    ACS APPLIED NANO MATERIALS, 2023, 6 (13) : 11037 - 11048
12345