Promotive effect of isopentane on cyclohexane isomerization catalyzed by sulfated zirconia

被引：8
|
作者：
Shimizu, K
Sunagawa, T
Arimura, K
Hattori, H
机构：
[1] AIST, Natl Inst Resources & Environm, Energy Resources Dept, Tsukuba, Ibaraki 3058569, Japan
[2] Sci Univ Tokyo, Fac Sci & Technol, Dept Ind Chem, Chiba 2788510, Japan
[3] Hokkaido Univ, Ctr Adv Res Energy Technol, Sapporo, Hokkaido 0608628, Japan
来源：
CATALYSIS LETTERS | 1999年 / 63卷 / 3-4期
关键词：
sulfated zirconia; cyclohexane isomerization; effect of solvent;
D O I：
10.1023/A:1019081424409
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cyclohexane isomerization to methylcyclopentane over sulfated zirconia is markedly enhanced in the presence of isopentane which acts as a hydride transfer agent to facilitate the slow step of hydride transfer from cyclohexane to isopropyl cation. This was revealed by deuterium tracer studies.
引用
收藏
页码：185 / 188
页数：4
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