Promotive effect of isopentane on cyclohexane isomerization catalyzed by sulfated zirconia

被引：8
|
作者：
Shimizu, K
Sunagawa, T
Arimura, K
Hattori, H
机构：
[1] AIST, Natl Inst Resources & Environm, Energy Resources Dept, Tsukuba, Ibaraki 3058569, Japan
[2] Sci Univ Tokyo, Fac Sci & Technol, Dept Ind Chem, Chiba 2788510, Japan
[3] Hokkaido Univ, Ctr Adv Res Energy Technol, Sapporo, Hokkaido 0608628, Japan
来源：
CATALYSIS LETTERS | 1999年 / 63卷 / 3-4期
关键词：
sulfated zirconia; cyclohexane isomerization; effect of solvent;
D O I：
10.1023/A:1019081424409
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Cyclohexane isomerization to methylcyclopentane over sulfated zirconia is markedly enhanced in the presence of isopentane which acts as a hydride transfer agent to facilitate the slow step of hydride transfer from cyclohexane to isopropyl cation. This was revealed by deuterium tracer studies.
引用
收藏
页码：185 / 188
页数：4
相关论文
共 50 条
  • [1] Promotive effect of isopentane on cyclohexane isomerization catalyzed by sulfated zirconia
    Kiyoyuki Shimizu
    Tomohito Sunagawa
    Keijiro Arimura
    Hideshi Hattori
    Catalysis Letters, 1999, 63 : 185 - 188
  • [2] Pentane isomerization and disproportionation catalyzed by sulfated zirconia promoted with iron and manganese
    Rezgui, S
    Gates, BC
    CATALYSIS LETTERS, 1996, 37 (1-2) : 5 - 8
  • [3] n-pentane isomerization and disproportionation catalyzed by promoted and unpromoted sulfated zirconia
    S. Rezgui
    R. E. Jentoft
    B. C. Gates
    Catalysis Letters, 1998, 51 : 229 - 234
  • [4] KINETICS OF ISOMERIZATION OF N-BUTANE AND OF ISOBUTANE CATALYZED BY PROMOTED SULFATED ZIRCONIA
    ZARKALIS, N
    HSU, CY
    GATES, BC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1993, 206 : 199 - COLL
  • [5] n-pentane isomerization and disproportionation catalyzed by promoted and unpromoted sulfated zirconia
    Rezgui, S
    Jentoft, RE
    Gates, BC
    CATALYSIS LETTERS, 1998, 51 (3-4) : 229 - 234
  • [6] α-Pinene isomerization to camphene: Effect of thermal treatment on sulfated zirconia
    Comelli, Nora A.
    Ponzi, Esther N.
    Ponzi, Marta I.
    Chemical Engineering Journal, 2006, 117 (02): : 93 - 99
  • [7] α-Pinene isomerization to camphene -: Effect of thermal treatment on sulfated zirconia
    Comelli, NA
    Ponzi, EN
    Ponzi, MI
    CHEMICAL ENGINEERING JOURNAL, 2006, 117 (02) : 93 - 99
  • [8] n-Butane Isomerization Catalyzed by Sulfated Zirconia Nanocrystals Supported on Silica or γ-Alumina
    Xiaobo Yang
    Rolf E. Jentoft
    Friederike C. Jentoft
    Catalysis Letters, 2006, 106 : 195 - 203
  • [9] n-Butane isomerization catalyzed by sulfated zirconia nanocrystals supported on silica or γ-alumina
    Yang, XB
    Jentoft, RE
    Jentoft, FC
    CATALYSIS LETTERS, 2006, 106 (3-4) : 195 - 203
  • [10] Sulfated zirconia-catalyzed alkylation of phenol with camphene and isomerization of n-butane
    Popova, Svetlana A.
    Chukicheva, Irina Yu
    Kutchin, Alexander V.
    Tarasov, Andrei L.
    Kustov, Leonid M.
    MENDELEEV COMMUNICATIONS, 2014, 24 (02) : 98 - 99
12345