Stereoselective synthesis of (-)-cytoxazone

被引：35
|
作者：
Carda, M [1 ]
González, F
Sánchez, R
Marco, JA
机构：
[1] Univ Jaume 1, Dept Quim Organ & Inorgan, E-12080 Castellon de La Plana, Spain
[2] Univ Valencia, Dept Quim Organ, E-46100 Valencia, Spain
来源：
TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 09期
关键词：
D O I：
10.1016/S0957-4166(02)00227-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The stereoselective synthesis of the cytokine modulator (-)-cytoxazone in enantiopure form is described. Key steps of the process are a syn-stereoselective aldol addition of a chiral ketone mediated by chlorodicyclohexylborane, and a Curtius rearrangement. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1005 / 1010
页数：6
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