Characterization of the irradiation-induced phase transition in the monoclinic polymorph of zirconia

Two groups of pure zirconia (ZrO2) specimens with the monoclinic polymorph and distinct nanopowder size ranges of approximately 20-30 nm and 30-60 nm were irradiated separately at room temperature with 100 keV H+ and 3 MeV Fe2+ ions to various fluences. Following TEM observations and XRD analyses, the irradiation with 100 keV protons to a fluence of over 3 x 10(15) ions/cm(2) was demonstrated to induce transformation from monoclinic (m) to tetragonal (t) phases in the specimen with the size range of approximately 20-30 nm due to the energy crossover that facilitates the m -> t transformation. However, the transformation did not occur in the irradiated specimen with the other size range even though the fluence of protons was up to 1 x 10(17) ions/cm(2). Furthermore, although irradiation with 3 MeV Fe2+ ions brought about low electronic energy loss, the m -> t transformation can be induced under the low fluence of 1 x 10(14) ions/cm(2) because a high level of damage defects (oxygen vacancies) may promote the m t transformation. Consequently, the largest crystallite size of t-ZrO2 induced by the proton irradiation is approximately 29 nm, as a result of the metastable critical size effect of t-phase zirconia at room temperature. (C) 2014 Elsevier B.V. All rights reserved.