crystal structure;
susceptibility magnetic;
electron paramagnetic resonance;
D O I:
10.1016/S0304-8853(01)01080-0
中图分类号:
T [工业技术];
学科分类号:
08 ;
摘要:
The magnetic susceptibility and electron paramagnetic resonance (EPR) of the Ti5Mn0.45Sb2.45 and Ti5CrSb2 compounds were investigated. The Ti5Mn0.45Sb2.45 and Ti5CrSb2 ternary compounds crystallize in W5Si3 structure type (14/mcm space group). Particularly, the crystal structure of new Ti5CrSb2 compound has been refined and their magnetic properties were measured in the 4.2-500K temperature ranges. The Peculiarities of observed magnetic properties of the Ti5Mn0.45Sb2.55 and Ti5CrSb2 compounds and valence state of chromium in the Ti5CrSb2 lattice are discussed. (C) 2002 Published by Elsevier Science B.V.
机构:
Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, RussiaMoscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
Morozkin, A. V.
Isnard, O.
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h-index: 0
机构:
Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
CNRS, Inst Neel, F-38042 Grenoble, France
Univ J Fourier, F-38042 Grenoble, FranceMoscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
Isnard, O.
Granovsky, S. A.
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机构:
Moscow MV Lomonosov State Univ, Dept Phys, Moscow 119991, RussiaMoscow MV Lomonosov State Univ, Dept Chem, Moscow 119992, Russia
机构:
North China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Peoples R ChinaNorth China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Peoples R China
He Qiang
Guo Yong-Quan
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机构:
North China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Peoples R ChinaNorth China Elect Power Univ, Sch Energy Power & Mech Engn, Beijing 102206, Peoples R China