Magnetic properties of ternary W5Si3-type compounds

被引:1
|
作者
Tkachuk, A
Gorelenko, Y
Padlyak, B
Jankowska-Frydel, A
Stadnyk, Y
机构
[1] Ivan Franko Natl Univ, Dept Inorgan Chem, UA-79005 Lvov, Ukraine
[2] Univ Gdansk, Inst Expt Phys, PL-80952 Gdansk, Poland
关键词
crystal structure; susceptibility magnetic; electron paramagnetic resonance;
D O I
10.1016/S0304-8853(01)01080-0
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The magnetic susceptibility and electron paramagnetic resonance (EPR) of the Ti5Mn0.45Sb2.45 and Ti5CrSb2 compounds were investigated. The Ti5Mn0.45Sb2.45 and Ti5CrSb2 ternary compounds crystallize in W5Si3 structure type (14/mcm space group). Particularly, the crystal structure of new Ti5CrSb2 compound has been refined and their magnetic properties were measured in the 4.2-500K temperature ranges. The Peculiarities of observed magnetic properties of the Ti5Mn0.45Sb2.55 and Ti5CrSb2 compounds and valence state of chromium in the Ti5CrSb2 lattice are discussed. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:901 / 903
页数:3
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